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Merck

407666

Ammonia solution

0.4 M in dioxane

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About This Item

Linear Formula:
NH3
CAS Number:
7664-41-7
Molecular Weight:
17.03
NACRES:
NA.55
PubChem Substance ID:
329755942
UNSPSC Code:
12352300
MDL number:
MFCD00011418
Concentration:
0.4 M in dioxane, 450-600 mmol/L (titration)
Form:
liquid

Key Documents

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InChI

1S/H3N/h1H3

SMILES string

N

InChI key

QGZKDVFQNNGYKY-UHFFFAOYSA-N

vapor pressure

11.73 psi ( 55 °C), 4.16 psi ( 20 °C)

form

liquid

concentration

0.4 M in dioxane, 450-600 mmol/L (titration)

density

1.023 g/mL at 25 °C

Quality Level

100

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General description

The product is a 0.4 M solution of ammonia in dioxane. Ammonia is a colorless gas with a characteristic strong odor. It is highly soluble in water, alcohol, chloroform and ether. It is extensively sold in the form of solution.1 Ammonia molecule is pyramidal in shape with nitrogen in the center and the three hydrogen atoms along the three vertices and the lone pair of electrons on the fourth vertex. Ammonia solution is commonly used as a base.

Application

Ammonia solution (0.4 M in dioxane) may be used in the synthesis of 8-nitroquinolin-2-amine and silphenylene-containing polymers.

signalword

Danger

Hazard Classifications

Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

EUH019,EUH066

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

123-91-1

CAS No.

123-91-1

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
0000482113
0000482114
0000482114
0000482113
0000442275

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Synthesis and properties of polymers containing silphenylene moiety via catalytic cross-dehydrocoupling polymerization of 1,4-bis (dimethylsilyl) benzene.
Li Y and Kawakami Y.
Macromolecules, 32(26), 8768-8773 (1999)
Discovery of a new antileishmanial hit in 8-nitroquinoline series.
Paloque L, et al.
European Journal of Medicinal Chemistry, 54, 75-86 (2012)
Eagleson M.
Concise Encyclopedia Chemistry, 65-66 (1994)
Patrick M Erwin et al.
The ISME journal, 8(3), 575-588 (2013-10-25)
Ascidians are ecologically important components of marine ecosystems yet the ascidian microbiota remains largely unexplored beyond a few model species. We used 16S rRNA gene tag pyrosequencing to provide a comprehensive characterization of microbial symbionts in the tunic of 42
Olivier Braissant et al.
Journal of inherited metabolic disease, 36(4), 595-612 (2012-10-31)
Hyperammonemia can be caused by various acquired or inherited disorders such as urea cycle defects. The brain is much more susceptible to the deleterious effects of ammonium in childhood than in adulthood. Hyperammonemia provokes irreversible damage to the developing central
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