632287
VenPure® SF
powder
Synonym(s):
Sodium borohydride, Sodium tetrahydridoborate
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About This Item
Linear Formula:
NaBH4
CAS Number:
Molecular Weight:
37.83
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
241-004-4
MDL number:
Form:
powder
form
powder
Quality Level
reaction suitability
reagent type: reductant
mp
>300 °C (dec.) (lit.)
SMILES string
[BH4-].[Na+]
InChI
1S/BH4.Na/h1H4;/q-1;+1
InChI key
YOQDYZUWIQVZSF-UHFFFAOYSA-N
Related Categories
Application
VenPure® SF (Sodium borohydride powder) is a mild reducing agent used in the reduction of aldehydes and ketones to their corresponding alcohols. It is generally inert to other functional groups such as epoxides, esters, nitriles and lactones. Along with carboxylic acid, it forms acyloxyborohydride, which is a versatile reducing agent to reduce indoles, quinolones, imines, enamines, oximes and enamides.
Legal Information
VenPure is a registered trademark of Ascensus Specialties LLC
signalword
Danger
hcodes
supp_hazards
Storage Class
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 3 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1B - Water-react. 1
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Sodium borohydride in carboxylic acid media: a phenomenal reduction system.
Gribble G W
Chemical Society Reviews, 27(6), 395-404 (1998)
Sodium borohydride.
Banfi L, et al.
e-EROS Encyclopedia of Reagents for Organic Synthesis., 1-13 (2014)
Forty years of hydride reductions.
Brown H C and Krishnamurthy S
Tetrahedron, 35(5), 567-607 (1979)
Qinghua Cui et al.
Analytica chimica acta, 724, 86-91 (2012-04-10)
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Jaydee D Cabral et al.
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