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Merck

104876

Trichlorovinylsilane

97%

Synonym(s):

(Trichlorosilyl)ethylene, Vinyltrichlorosilane

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About This Item

Linear Formula:
H2C=CHSiCl3
CAS Number:
Molecular Weight:
161.49
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
200-917-8
Beilstein/REAXYS Number:
1743440
MDL number:
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vapor density

>1 (vs air)

Quality Level

vapor pressure

60 mmHg ( 23 °C)

assay

97%

refractive index

n20/D 1.436 (lit.)

bp

90 °C (lit.)

mp

−95 °C (lit.)

density

1.27 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

Cl[Si](Cl)(Cl)C=C

InChI

1S/C2H3Cl3Si/c1-2-6(3,4)5/h2H,1H2

InChI key

GQIUQDDJKHLHTB-UHFFFAOYSA-N

General description

Trichlorovinylsilane may react with lithium-tert-butyl, and 1,3-enynes to yield isomeric silacyclobutanes and silacyclobutenes respectively.

Application

A study reports the possible use of this silane for treating Pluronic F127, chitosan for better attachment and proliferation of endothelial cells on biomaterials. Trichlorovinylsilane may be used to prepare epoxy terminated carbosiloxane.

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A

Storage Class

3 - Flammable liquids

wgk

WGK 1

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Yu Chi Wang et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 18(3), 525-527 (2004-01-13)
Controlling the spatial organization of cells is vital in engineering tissues that require precisely defined cellular architectures. For example, functional nerves or blood vessels form only when groups of cells are organized and aligned in very specific geometries. Yet, scaffold
Xiangming Wu et al.
Colloids and surfaces. B, Biointerfaces, 130, 69-76 (2015-04-25)
Earlier work provided direction for development of responsive drug delivery systems based on modulation of the structure, amphiphilicity, and surface density of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. In this work, we describe the sequential and
Micropatterning of proteins and mammalian cells on biomaterials.
Faseb Journal, 18(3), 525-527 (2004)
Trichlorovinylsilane, lithium-tert-butyl, and 1, 3-enynes: A versatile combination for the competitive formation of silacyclobutanes and silacyclobutenes.
Canadian Journal of Chemistry, 78(11), 1445-1458 (2000)
Efstratios Mitridis et al.
ACS nano, 14(9), 11712-11721 (2020-08-17)
Imparting and maintaining surface superhydrophobicity has been receiving significant research attention over the last several years, driven by a broad range of important applications and enabled by advancements in materials and surface nanoengineering. Researchers have investigated the effect of temperature

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