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Merck

544841

Cerium oxide

greener alternative

nanopowder, <25 nm particle size (BET)

Synonym(s):

Cerium dioxide, Cerium(IV) oxide, Ceric oxide, Ceric oxide, ceria

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About This Item

Linear Formula:
CeO2
CAS Number:
Molecular Weight:
172.11
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
215-150-4
MDL number:
eCl@ss:
38160411
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Product Name

Cerium(IV) oxide, nanopowder, <25 nm particle size (BET)

form

nanopowder

Quality Level

reaction suitability

reagent type: catalyst
core: cerium

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

particle size

<25 nm (BET)

density

7.13 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

SMILES string

O=[Ce]=O

InChI

1S/Ce.2O

InChI key

CETPSERCERDGAM-UHFFFAOYSA-N

General description

Cerium(IV)oxide (CeO₂), also known as ceric oxide, ceria, or cerium dioxide, is an oxide of the rare-earth metal cerium. It appears as a white to yellow nanopowder with a particle size of less than 25 nm (BET), exhibiting high surface area and reactivity. It is used in various applications, including catalysis, electrochemical applications, and in glass and ceramics. CeO₂ is widely employed in catalytic converters for automotive applications, where it aids in the reduction of harmful emissions. Additionally, it is used in the production of advanced ceramics, glass polishing, and as a catalyst in various chemical reactions. Its unique properties also make it valuable in solid oxide fuel cells and as a UV filter in sunscreens.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is intended for Molecular Solar Thermal Energy Storage Systems (MOST) and has been enhanced for energy efficiency. Click here for more information.

Application

CeO2nanopowder is utilized in solid oxide fuel cells (SOFCs) due to its ionicconductivity and stability at high temperatures. It is also used in batteriesand supercapacitors to improve performance. Additionally, CeO2 is used as a polishing powder in the glass andsemiconductor industries. Its fine particle size and hardness make it effectivefor achieving high surface finishes on optical components.
The additon of CeO2 to CuO/TiO2 increases specific surface area and inhibits sintering and pore size growth at high temperatures.

Legal Information

Product of Engi-Mat Co.


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Storage Class

11 - Combustible Solids

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges



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Dengsong Zhang et al.
Nanoscale, 5(3), 1127-1136 (2013-01-04)
The MnO(x) and CeO(x) were in situ supported on carbon nanotubes (CNTs) by a poly(sodium 4-styrenesulfonate) assisted reflux route for the low-temperature selective catalytic reduction (SCR) of NO with NH(3). X-Ray diffraction (XRD), transmission electron microscopy (TEM), high-resolution TEM (HRTEM)
Gao Li et al.
Chemical communications (Cambridge, England), 48(98), 12005-12007 (2012-11-07)
The Au(25)(SR)(18)/CeO(2) nanocluster catalyst showed high activity in the homocoupling of aryl iodides (e.g. up to 99.8% yield with iodobenzene) and excellent recyclability.
Zhen-Xing Li et al.
Nanoscale, 5(3), 1213-1220 (2013-01-10)
Translation of homogeneous catalysis into heterogeneous catalysis is a promising solution to green and sustainable development in chemical industry. For this purpose, noble metal nanoparticles represent a new frontier in catalytic transformations. Many challenges remain for researchers to transform noble