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703540

2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物 溶液

1.0 M in THF

别名:

TMPMgCl·LiCl

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关于此项目

经验公式（希尔记法）:
C9H18Cl2LiMgN
化学文摘社编号:
898838-07-8
分子量:
242.40
NACRES:
NA.22
PubChem Substance ID:
329762048
UNSPSC Code:
12352103
MDL number:
MFCD12546030
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form

liquid

Quality Level

100

reaction suitability

reaction type: Grignard Reaction

packaging

Sure/Seal™ of

concentration

1.0 M in THF, 20 % (w/w)

density

0.96 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

[Li+].[Cl-].CC1(C)CCCC(C)(C)N1[Mg]Cl

InChI

1S/C9H18N.2ClH.Li.Mg/c1-8(2)6-5-7-9(3,4)10-8;;;;/h5-7H2,1-4H3;2*1H;;/q-1;;;+1;+2/p-2

InChI key

JHBZAAACZVPPRQ-UHFFFAOYSA-L

Application

使用Knochel-Hauser碱的选择性去质子化
2,2,6,6-四甲基哌啶基氯化镁氯化锂复合物是非亲核性Knochel-Hauser碱， 主要用于官能化芳烃和杂芳烃的氧化，以制备相应的格氏试剂。它还可以用作通过催化剂转移缩聚合成Π-共轭聚合物过程的碱。

Packaging

建议将25 mL Sure/Seal™ 瓶作为一次性包装瓶使用。 反复穿刺可能导致产品性能下降。

Legal Information

Albemarle US Inc.产品
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

supp_hazards

EUH014,EUH019

存储类别

3 - Flammable liquids

flash_point_f

5.0 °F

flash_point_c

-15 °C

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3

target_organs

Central nervous system, Respiratory system

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBP2181
SHBN9202
SHBM6948
SHBL7221
SHBL3467

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Direct, regioselective N-alkylation of 1, 3-azoles.
Chen S
Organic Letters, 18(1), 16-19 (2015)
Highly Functionalized Benzene Syntheses by Directed Mono or Multiple Magnesiations with TMPMgCl.LiCl.
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Organic Letters, 8(24), 5673-5676 (2006)
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