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Merck

761311

cataCXium® A Pd G2

solid

别名:

cataCXium A-Pd-G2, 氯[(二(1-金刚烷基)-N-丁基膦)-2-(2-氨基-联苯)]钯(II)

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关于此项目

经验公式(希尔记法):
C36H49ClNPPd
化学文摘社编号:
分子量:
668.63
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Form:
solid
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产品名称

cataCXium® A Pd G2,

Quality Segment

product line

Buchwald precatalyst Generation 2

form

solid

feature

generation 2

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings

mp

220 °C (decomposition)

functional group

amine, phosphine

SMILES string

Nc1ccccc1-c2ccccc2[Pd]Cl.CCCCP([C@@]34C[C@@H]5C[C@@H](C[C@@H](C5)C3)C4)[C@@]67C[C@@H]8C[C@@H](C[C@@H](C8)C6)C7

InChI

1S/C24H39P.C12H10N.ClH.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;;/h17-22H,2-16H2,1H3;1-6,8-9H,13H2;1H;/q;;;+1/p-1/t17-,18+,19-,20-,21+,22-,23-,24-;;;

InChI key

CAVPLNLGXHYGIR-DVBMAMJVSA-M

Application

cataCXium® A Pd G2是Buchwald′的第二代催化剂,可作为钯源用于通过Suzuki-Miyaura反应偶联1-(苄氧基)烷基三氟硼酸钾与芳基和杂芳基氯化物,以形成保护二级醇。

Legal Information

cataCXium is a registered trademark of Umicore AG & Co. KG


存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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