10452
Ruthenium(III) chloride trihydrate
technical grade, solid
Synonym(s):
Ruthenium trichloride trihydrate
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About This Item
Linear Formula:
RuCl3 · 3H2O
CAS Number:
Molecular Weight:
261.47
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
Product Name
Ruthenium(III) chloride trihydrate, technical
SMILES string
O.O.O.Cl[Ru](Cl)Cl
InChI
1S/3ClH.3H2O.Ru/h3*1H;3*1H2;/q;;;;;;+3/p-3
InChI key
ZTWIEIFKPFJRLV-UHFFFAOYSA-K
grade
technical
form
solid
reaction suitability
core: ruthenium, reaction type: C-H Activation, reagent type: catalyst
Quality Level
Application
Ruthenium(III) chloride trihydrate can be used as a catalyst:
- Precursor for the hydroamidation of terminalalkynes.
- For the hydrolysis of 4-nitrobenzonitrile to 4-nitrobenzamide in the presence of 1,3,5-triaza-7-phosphaadamantane.
- For the oxidation of thioethers to sulfones in the presence of sodium periodate and acetonitrile.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
Storage Class
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Jaouhari, R.; Guenot, P.; Dixneuf, P. H.
Chemical Communications (Cambridge, England), 1255-1255 (1986)
Tenaglia, A.; Terranova, E. et al.
Tetrahedron Letters, 32, 1169-1169 (1991)
A Practical and Effective Ruthenium Trichloride-Based Protocol for the Regio-and Stereoselective Catalytic Hydroamidation of Terminal Alkynes
Goossen L, et al.
advanced synthesis and catalysis, 350, 2701-2707 (2008)
Whalmany L Ounkham et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(42), 10013-10020 (2019-05-18)
RuCl2 (PTA)4 (PTA=1,3,5-triaza-7-phosphaadamantane) is an active, recyclable, air-stable, aqueous-phase nitrile hydration catalyst. The development of an in situ generated aqueous-phase nitrile hydration catalyst (RuCl3 ⋅3 H2 O+6 equivalents PTA) is reported. The activity of the in situ catalyst is comparable to RuCl2
Baskaran Purushothaman et al.
European journal of medicinal chemistry, 156, 747-759 (2018-07-27)
Ruthenium(II/III) metal complexes have been widely recognized as the alternative chemotherapeutic agents to overcome the drug resistance and tumor recurrence associated with platinum derivatives. In this work, a novel ruthenium(II) triazine complex namely, 1 ([Ru(bdpta)(tpy)]2+) was synthesized and spectroscopically characterized.
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