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32950

4,4′-Diaminodiphenylmethane

≥97.0% (GC)

Synonym(s):

4,4′-Methylenedianiline, MDA

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About This Item

Empirical Formula (Hill Notation):
C13H14N2
CAS Number:
101-77-9
Molecular Weight:
198.26
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
57648737
EC Number:
202-974-4
Beilstein/REAXYS Number:
474706
MDL number:
MFCD00007914
Assay:
≥97.0% (GC)
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Quality Level

100

assay

≥97.0% (GC)

mp

88-92 °C

solubility

water: soluble

SMILES string

Nc1ccc(Cc2ccc(N)cc2)cc1

InChI

1S/C13H14N2/c14-12-5-1-10(2-6-12)9-11-3-7-13(15)8-4-11/h1-8H,9,14-15H2

InChI key

YBRVSVVVWCFQMG-UHFFFAOYSA-N

Gene Information

mouse ... Slc6a2(20538)
rat ... Slc6a3(24898), Slc6a4(25553)

General description

4,4′-diaminodiphenylmethane acts as a bidentate-bridging ligand, forming hydrogen bonds with its amine hydrogen atoms, and also participates in several non-covalent interactions.

Application

4,4′-Diaminodiphenylmethane was employed:
  • as dummy template for bisphenols imprinting
  • in the synthesis of amino modified multi-walled carbon nanotubes/polydimethylsiloxane
  • as curing agent to study the kinetics of formation of epoxy resin composites
  • in rubber industry as an epoxyresin hardener

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Muta. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1

target_organs

Liver, Liver,eye - retina

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

429.8 °F - closed cup

flash_point_c

221 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

101-77-9

CAS No.

101-77-9

CAS No.

101-77-9

CAS No.

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Certificates of Analysis (COA)

Lot/Batch Number
BCCP6645
BCCP6644
BCCN9248
BCCN9247
BCCM7223

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Six transition metal--organic materials with the ditopic 4, 4?-diaminodiphenylmethane ligand: Synthesis, structure characterization and luminescent properties
Chisca D, et al.
Polyhedron, 192, 114844-114844 (2020)
Bing Yu et al.
Journal of ethnopharmacology, 165, 173-179 (2015-02-25)
Fuzi [the lateral root of Aconitum carmichaeli Debx (Ranunculaceae)] is a well-known traditional medicinal herb used to treat chronic heart failure (CHF). Aconitine-type alkaloids are major alkaloids that are responsible for the pharmacological activity and toxicity of this herb.To investigate
Carcinogenic and chronic effects of 4,4'-diaminodiphenylmethane, an epoxyresin hardener.
R Schoental
Nature, 219(5159), 1162-1163 (1968-09-14)
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