Sign In to View Organizational & Contract Pricing.
Select a Size
Change View
About This Item
Linear Formula:
Ni(C5H7O2)2
CAS Number:
Molecular Weight:
256.91
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
221-875-7
Beilstein/REAXYS Number:
4157970
MDL number:
Quality Level
assay
95%
form
solid
reaction suitability
core: nickel, reagent type: catalyst
mp
230 °C (dec.) (lit.)
SMILES string
CC(=O)\C=C(\C)O[Ni]O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
InChI key
BMGNSKKZFQMGDH-FDGPNNRMSA-L
General description
Nickel(II) acetylacetonate (Ni(acac)₂) is a high-purity, air-stable organometallic complex widely used as a catalyst and precursor in advanced material synthesis. Its chelated structure provides excellent solubility in organic solvents and thermal stability, making it suitable for solution and vapor deposition processes. Ni(acac)₂ is used in the fabrication of energy materials, nanostructures, and functional coatings. Its versatility and reactivity enable applications in catalysis, electronic materials, and the synthesis of high-performance inorganic compounds.
Application
Nickel(II) acetylacetonate can be used as:
- A precursor in sol-gel and hydrothermal processes to synthesize nickel oxide (NiO) nanostructures and thin films, which are widely applied in catalysis, energy storage (supercapacitors, batteries), and gas sensors.
- A precursor for chemical vapor deposition (CVD) and atomic layer deposition (ALD) of nickel-containing films, enabling the fabrication of high-purity, uniform coatings for electronic and magnetic devices.
- A catalyst or catalyst precursor in organic transformations and electrocatalysis, such as hydrogen evolution, oxygen evolution, and CO₂ reduction reactions, due to its ability to generate highly active nickel species under reaction conditions.
- A precursor to synthesize Ni-based nanomaterials such as NiO/C nanocomposite and crystalline NiO nanoparticles via different synthetic methods like non-isothermal decomposition and solvothermal method.
- A precursor to prepare Ni catalysts such as Nickel(II) complexes, and hierarchical Ni/beta catalysts for various organictransformations.
- A catalyst to promote Michael additions.
Features and Benefits
- High Purity and Stability: Available in high-purity grades and exhibits excellent thermal and chemical stability
- Solubility: Soluble in a wide range of organic solvents, enhancing its versatility in various synthesis and deposition processes
- User-Friendly Handling: Its solubility and stability simplify storage, handling, and integration into various chemical processes
signalword
Danger
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
428.0 °F
flash_point_c
220 °C
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1
Choose from one of the most recent versions:
Already Own This Product?
Find documentation for the products that you have recently purchased in the Document Library.
Lin Chen et al.
Nature communications, 8, 14136-14136 (2017-01-11)
Incorporating oxophilic metals into noble metal-based catalysts represents an emerging strategy to improve the catalytic performance of electrocatalysts in fuel cells. However, effects of the distance between the noble metal and oxophilic metal active sites on the catalytic performance have
Husileng Lee et al.
ChemSusChem, 13(12), 3277-3282 (2020-04-02)
Water oxidation is the bottleneck reaction in artificial photosynthesis. Exploring highly active and stable molecular water oxidation catalysts (WOCs) is still a great challenge. In this study, a water-soluble NiII complex bearing a redox non-innocent tetraamido macrocyclic ligand (TAML) is
Huiming Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(45), 11748-11754 (2018-06-06)
The phase of nanocrystals has a key role in the modulation of catalytic properties. Uniform and well-crystallized nickel phosphide nanocrystals with controlled phases (Ni5 P4 , Ni2 P, and Ni12 P5 ) and narrow size distributions are synthesized by a


