359009
Cerium(IV) sulfate
powder
Synonym(s):
Ceric sulfate, Cerium disulfate
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About This Item
Linear Formula:
Ce(SO4)2
CAS Number:
Molecular Weight:
332.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
237-029-5
MDL number:
Product Name
Cerium(IV) sulfate,
form
powder
Quality Level
reaction suitability
core: cerium, reagent type: catalyst
density
3.01 g/mL at 25 °C (lit.)
SMILES string
[Ce+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O
InChI
1S/Ce.2H2O4S/c;2*1-5(2,3)4/h;2*(H2,1,2,3,4)/q+4;;/p-4
InChI key
VZDYWEUILIUIDF-UHFFFAOYSA-J
Application
Reactant for:
- Preparation of spherical-like nanoparticles CeO2 nanoparticles for NO reductions reactions
- Oxidizing agent
Cerium(IV) sulfate can be used to catalyze:
- Selective oxidation of secondary alcohols to the corresponding ketones using sodium bromate as the oxidant.
- Direct sulfonation of methane with sulfur trioxide to methanesulfonic acid in sulfuric acid.
- Synthesis of 14-aryl- or 14-alkyl-14H-dibenzo[aj]xanthenes from the condensation of 2-naphthol and aldehydes under solvent-free and microwave conditions.
Other Notes
may contain excess sulfate
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B
Storage Class
8B - Non-combustible corrosive hazardous materials
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Toshio Yao et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(6), 829-833 (2003-07-02)
A flow injection biosensor system was proposed for the highly sensitive detection of 2,4,6-trichlorophenol (2,4,6-TCP). The system is based on the preoxidation by ceric sulfate to the corresponding benzoquinone (2,6-dichloro-1,4-benzoquinone: 2,6-DC-1,4-BQ), which was characterized using cyclic voltammetry, hydrodynamic voltammetry, and
Hidayat Hussain et al.
Chemistry & biodiversity, 12(2), 289-294 (2015-02-14)
A new polychlorinated triphenyl diether named microsphaerol (1), has been isolated from the endophtic fungus Microsphaeropsis sp. An intensive phytochemical investigation of the endophytic fungus Seimatosporium sp., led to the isolation of a new naphthalene derivative named seimatorone (2) and
S M Sultan et al.
Journal of pharmaceutical and biomedical analysis, 7(3), 279-286 (1989-01-01)
A simple and accurate kinetic method for the determination of propranolol has been developed. Cerium(IV) sulphate (0.5 M) is used to oxidize propranolol in 2 M sulphuric acid at room temperature to the ketone form that absorbs light at a