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375934

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide

≥95%, with 1% tert-Butyldimethylchlorosilane

Synonym(s):

MTBSTFA+TBDMSCl, 99:1, N-Methyl-N-tert-butyldimethylsilyltrifluoroacetamide, MTBSTFA + 1% TBDMSCl, Silylating mixture VI

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About This Item

Empirical Formula (Hill Notation):
C9H18F3NOSi
CAS Number:
77377-52-7
Molecular Weight:
241.33
UNSPSC Code:
12352001
PubChem Substance ID:
24863412
NACRES:
NA.22
Beilstein/REAXYS Number:
3606546
MDL number:
MFCD00009671
Assay:
≥95%
Form:
liquid
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Product Name

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide with 1% tert-Butyldimethylchlorosilane, ≥95%

Quality Segment

100

assay

≥95%

form

liquid

contains

1% TBDMSCl

reaction suitability

reactivity: alcohol reactive, reactivity: amine reactive, reagent type: protection reagent

functional group

amine, fluoro

storage temp.

−20°C

SMILES string

CN(C(=O)C(F)(F)F)[Si](C)(C)C(C)(C)C

InChI

1S/C9H18F3NOSi/c1-8(2,3)15(5,6)13(4)7(14)9(10,11)12/h1-6H3

InChI key

QRKUHYFDBWGLHJ-UHFFFAOYSA-N

Application

N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide with 1% tert-butyldimethylchlorosilane is commonly used for the preparation of N-tert-butyldimethylsilyl ethanolamines resulting from the hydrolysis of nitrogen mustards. It is also used for selective O-silylation of N,O-diacylhydroxyl amines.

Disclaimer

Supply conditions do not apply to the regions and states of Brazil: North, Northeast, Mato Grosso do Sul, Mato Grosso, and Rio Grande do Sul.

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pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

113.0 °F - closed cup

flash_point_c

45 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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