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About This Item
Linear Formula:
CH2(COONa)2
CAS Number:
Molecular Weight:
148.03
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
205-514-0
Beilstein/REAXYS Number:
3917013
MDL number:
Assay:
≥97.0% (NT)
Form:
solid
Product Name
Sodium malonate dibasic, ≥97.0% (NT)
InChI key
PRWXGRGLHYDWPS-UHFFFAOYSA-L
InChI
1S/C3H4O4.2Na/c4-2(5)1-3(6)7;;/h1H2,(H,4,5)(H,6,7);;/q;2*+1/p-2
SMILES string
[Na+].[Na+].[O-]C(=O)CC([O-])=O
assay
≥97.0% (NT)
form
solid
Quality Level
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Application
Sodium malonate dibasic can be use in the synthesis of sodium carbonate and sodium oxalate via wet oxidation and catalytic wet oxidation. It can also be used to synthesize malonato-bridged manganese(II)complexes like [Mn(mal)(H2O)2]n and [Mn2(mal)2(4,4′-bipy)(H2O)2]n,(bipy =bipyridine, mal =malonate), which have the tendency to show weak anti-ferromagnetic effect.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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"Magneto- structural correlations in 2D and 3D extended structures of manganese (II)- malonate systems"
Maji KT, et al.
Inorganic Chemistry, 42(03), 709-716 (2003)
"Selective organic removal from the alumina industrial liquor: Wet oxidation and catalytic wet oxidation of disodium malonate"
Eyer S , et al.
Industrial & Engineering Chemistry Research, 41(05), 1166-1170 (2002)
Wei-Shen Li et al.
Physical review. E, Statistical, nonlinear, and soft matter physics, 85(6 Pt 2), 066132-066132 (2012-09-26)
A chlorine-iodine-malonic-acid Turing system involving a local concentration-dependent diffusivity (LCDD) has fundamental significance for physical, chemical, and biological systems with inhomogeneous medium. We investigated such a system by both numerical computation and mathematical analysis. Our research reveals that a variable
Waree Limwikrant et al.
International journal of pharmaceutics, 431(1-2), 237-240 (2012-04-28)
A new 2/1 carbamazepine (CBZ)/malonic acid (MA) cocrystal polymorph form C was formed using a vibrational rod mill, whereas the known cocrystal polymorph form A was prepared using a ball mill. IR measurements showed that the interaction between CBZ and
Arturo Orellana et al.
The Journal of organic chemistry, 77(12), 5286-5296 (2012-05-04)
An efficient synthesis of (-)-kainic acid, through a high-pressure-promoted Diels-Alder cycloaddition of a vinylogous malonate derived from 4-hydroxyproline, is described. The bicyclic adduct could be converted into the natural product with complete stereocontrol.
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