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Merck

M2284

Manganese(III) acetylacetonate

technical grade

Synonym(s):

2,4-Pentanedione manganese(III) derivative, Manganic acetylacetonate, Mn(acac)3

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About This Item

Linear Formula:
Mn(C5H7O2)3
CAS Number:
14284-89-0
Molecular Weight:
352.26
NACRES:
NA.22
PubChem Substance ID:
24896721
UNSPSC Code:
12161600
EC Number:
238-188-3
MDL number:
MFCD00000023

Key Documents

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InChI key

HYZQBNDRDQEWAN-LNTINUHCSA-K

InChI

1S/3C5H8O2.Mn/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Mn](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

grade

technical grade

reaction suitability

core: manganese, reagent type: catalyst

Quality Level

100

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Related Categories

Application

Oxidant used to oxidize phenols, β-dicarbonyl compounds, and thiols.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB6430
STBL2811
STBJ9472
STBJ4448
STBH3677

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Nishino, H. Tategami, S. et al.
Bulletin of the Chemical Society of Japan, 64, 1800-1800 (1991)
Snider, B. B.; Patricia, J. J. et al.
The Journal of Organic Chemistry, 53, 2137-2137 (1988)
Gui-Ge Hou et al.
Chemical communications (Cambridge, England), 47(38), 10731-10733 (2011-08-27)
Two NbO-type MOFs based on ditopic pyridyl substituted diketonate ligands were reported. One exhibits a reversible SC-SC water encapsulation, while the other shows an interesting guest-driven luminescent property based on M(III) acetylacetonate (M = Eu and Fe) guest species.
David N Paglia et al.
Journal of orthopaedic research : official publication of the Orthopaedic Research Society, 30(12), 1971-1978 (2012-06-02)
This study quantified the effects of local intramedullary delivery of an organic vanadium salt, which may act as an insulin-mimetic on fracture healing. Using a BB Wistar rat femoral fracture model, local vanadyl acetylacetonate (VAC) was delivered to the fracture
Chih-Chia Huang et al.
Chemical communications (Cambridge, England), (23)(23), 3360-3362 (2009-06-09)
A general approach involving a solvothermal method was developed to synthesize a series of silicate nanoshells (<100 nm) where both Gd silicate and Gd silicate:Eu nanoshells were further demonstrated to exhibit dual-modality MRI and optical imaging functions.
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