510068
Raney®-Nickel
W.R. Grace and Co. Raney® 3202, slurry, in H2O, active catalyst
Synonym(s):
Nickel sponge
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About This Item
Linear Formula:
AlNi
CAS Number:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
eCl@ss:
38190701
Quality Level
form
slurry
reaction suitability
core: nickel, reagent type: catalyst
manufacturer/tradename
W.R. Grace and Co. Raney® 3202
concentration
in H2O
SMILES string
[Al].[Ni]
InChI
1S/Al.Ni
InChI key
NPXOKRUENSOPAO-UHFFFAOYSA-N
Application
Useful as a selective reducing agent for hydrogenation of organic compounds
Legal Information
Raney is a registered trademark of W.R. Grace & Co.-Conn.
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1
Storage Class
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 2
flash_point_f
Not applicable
flash_point_c
Not applicable
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Nitrile reduction in the presence of Boc-protected amino groups by catalytic hydrogenation over palladium-activated Raney-nickel.
B Klenke et al.
The Journal of organic chemistry, 66(7), 2480-2483 (2001-04-03)
Tsukinoki, T.; Kanda, T.
Tetrahedron Letters, 41, 5865-5865 (2000)
Barrero, A. F.; Alvarez-Manzaneda, E. J. et al.
Synthesis, 197-197 (2000)