Skip to Content
Merck

P51001

Propargyl bromide solution

80 wt. % in toluene, contains 0.3% magnesium oxide as stabilizer

Synonym(s):

3-Bromo-1-propyne

Sign In to View Organizational & Contract Pricing.

Select a Size


About This Item

Linear Formula:
HC≡CCH2Br
CAS Number:
Molecular Weight:
118.96
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
605309
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Propargyl bromide solution, 80 wt. % in toluene, contains 0.3% magnesium oxide as stabilizer

InChI

1S/C3H3Br/c1-2-3-4/h1H,3H2

SMILES string

BrCC#C

InChI key

YORCIIVHUBAYBQ-UHFFFAOYSA-N

assay

13-27 %

form

liquid

contains

0.3% magnesium oxide as stabilizer

concentration

80 wt. % in toluene

refractive index

n20/D 1.494

bp

88-90 °C

density

1.335 g/mL at 25 °C

storage temp.

2-8°C

Quality Level

Looking for similar products? Visit Product Comparison Guide

Application

Used to make propargylic amines employed in enyne metathesis.
Employed in the propargylation of spiro ketones, allylic alcohols, and enone complexes.

General description

Propargyl bromide solution is used to prepare Grignard reagent and in the synthesis of propargylated lignin.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

target_organs

Central nervous system, Respiratory system

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

64.4 °F - closed cup

flash_point_c

18 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Renewable Thiol--yne ?Click? Networks Based on Propargylated Lignin for Adhesive Resin Applications
Monika J A et al.
ACS applied polymer materials, 4, 2544-2552 (2022)
Synthetic Communications, 24, 2159-2159 (1994)
Tetrahedron Letters, 48, 1927-1927 (2007)
Propargylmagnesium Bromide
Godson C and Nwokogu
e-EROS Encyclopedia of Reagents for Organic Synthesis (2001)
The Journal of Organic Chemistry, 58, 7782-7782 (1993)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service