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Merck

201049

Lithium hydride

greener alternative

powder, −30 mesh, ≥95%

Synonym(s):

LiH

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About This Item

Linear Formula:
LiH
CAS Number:
Molecular Weight:
7.95
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
26111700
EC Number:
231-484-3
MDL number:
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Quality Level

assay

≥95%

form

powder

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

particle size

−30 mesh

mp

680 °C (lit.)

density

0.82 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li]

InChI

1S/Li.H

InChI key

SIAPCJWMELPYOE-UHFFFAOYSA-N

General description

Lithium hydride is a simple neutral heteropolar diatomic molecule. It liberates hydrogen upon heating it to temperatures above 500oC. Lithium hydride, like lithium aluminum hydride, exhibits a high gravimetric hydrogen storage capacity. LiH is known to have large specific heat and latent heat of fusion.5
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Application

Lithium hydride may be used as an effective neutron shield for mobile nuclear reactors. LiH may also be used as a rocket fuel, energy storage system, and heat shield.5


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signalword

Danger

supp_hazards

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Acute Tox. 3 Oral - Skin Corr. 1B - Water-react. 1



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Thermophysical Properties of Chemicals and Hydrocarbons null
Spectroscopy and structure of the lithium hydride diatomic molecules and ions.
Stwalley WC and Zemke WT
The Journal of Physical Chemistry, 22(1), 87-112 (1993)
Lithium hydride: A space age shielding material
Welch FH
Nuclear Engineering and Design, 26(3), 444-460 (1974)