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Merck

115819

2,2′-Biphenol

99%

Synonym(s):

2,2′-Biphenyldiol, 2,2′-Dihydroxybiphenyl, 2,2′-Diphenol

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About This Item

Linear Formula:
HOC6H4C6H4OH
CAS Number:
Molecular Weight:
186.21
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
217-303-0
Beilstein/REAXYS Number:
1638363
MDL number:
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InChI key

IMHDGJOMLMDPJN-UHFFFAOYSA-N

InChI

1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H

SMILES string

Oc1ccccc1-c2ccccc2O

assay

99%

form

solid

bp

315 °C (lit.)

mp

108-110 °C (lit.)

Quality Level

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

309.2 °F - closed cup - (External MSDS)

flash_point_c

154 °C - closed cup - (External MSDS)

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Christina DiMarco-Crook et al.
Journal of food science, 85(4), 1292-1301 (2020-03-08)
Chemoprevention strategies employing the use of multiple dietary bioactive components and their metabolites in combination offer advantages due to their low toxicity and potential synergistic interactions. Herein, for the first time, we studied the combination of curcumin and 3',4'-didemethylnobiletin (DDMN)
Sierra Rayne et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 4(11), 876-886 (2005-10-28)
Photochemical studies on a range of model dibenzo[1,4]dioxins were performed in aqueous and organic solutions. The compounds were found to undergo a photochemically initiated aryl-ether bond homolysis that yields reactive 2-spiro-6'-cyclohexa-2',4'-dien-1'-one and subsequent 2,2'-biphenylquinone intermediates. Under steady-state irradiation, the 2,2'-biphenylquinones
W A Prütz et al.
International journal of radiation biology and related studies in physics, chemistry, and medicine, 44(2), 183-196 (1983-08-01)
Phenoxyl radicals generated pulse radiolytically by the reaction of N.3 with Gly-Tyr decay biomolecularly (2k = 4.7 X 10(8)M-1 s-1) with efficient formation of 2,2'-dimers, which enolize rapidly (k = 2.7 X 10(4) s-1) to produce the 2,2'-biphenolic product. The
H P Kohler et al.
Applied and environmental microbiology, 54(11), 2683-2688 (1988-11-01)
Pseudomonas sp. strain HBP1 was found to grow on 2-hydroxy- and 2,2'-dihydroxy-biphenyl as the sole carbon and energy sources. The first step in the degradation of these compounds was catalyzed by an NADH-dependent monooxygenase. The enzyme inserted a hydroxyl group
Bernd Schmidt et al.
The Journal of organic chemistry, 78(17), 8680-8688 (2013-08-01)
User-friendly protocols for the protecting group-free synthesis of 2,2'-biphenols via Suzuki-Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available

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