755745
2,2′-Azobis(2-methylpropionitrile)
recrystallized from methanol, 99%
Synonym(s):
α,α′-Azoisobutyronitrile, AIBN, Azobisisobutyronitrile, Free radical initiator
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About This Item
Linear Formula:
(CH3)2C(CN)N=NC(CH3)2CN
CAS Number:
Molecular Weight:
164.21
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
EC Number:
201-132-3
Beilstein/REAXYS Number:
1708400
MDL number:
Product Name
2,2′-Azobis(2-methylpropionitrile), recrystallized from methanol, 99%
InChI key
OZAIFHULBGXAKX-VAWYXSNFSA-N
InChI
1S/C8H12N4/c1-7(2,5-9)11-12-8(3,4)6-10/h1-4H3/b12-11+
SMILES string
CC(C)(\N=N\C(C)(C)C#N)C#N
assay
99%
form
crystals
mp
102-104 °C (dec.) (lit.)
103-107 °C
storage temp.
−20°C
Quality Level
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Related Categories
Application
- Porous Acid-Base Hybrid Polymers for Enhanced NH3 Uptake: This study discusses the use of 2,2′-Azobis(2-methylpropionitrile) in the synthesis of acid-base hybrid polymers, highlighting its role in enhancing ammonia uptake through cooperative hydrogen bonds (X Luo, Y Liu, et al., 2023).
- Extraction of Fluoroquinolones from Milk: The development of molecularly imprinted polymers using 2,2′-Azobis(2-methylpropionitrile) as an initiator for the extraction of antibiotics from milk showcases its application in food safety and pharmaceutical analysis (E Megias-Pérez, et al., 2023).
- Thermo-responsive Copolymer Visible Light Catalyst: Highlighting the use of 2,2′-Azobis(2-methylpropionitrile) in the synthesis of thermo-responsive copolymers, this study explores its applications in catalysis and material science, particularly in photoreactive polymers (S Wu, et al., 2024).
General description
This AIBN was recrystallized and is ready for use as a polymerization initiator.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Self-react. C
supp_hazards
Storage Class
4.1A - Other explosive hazardous materials
wgk
WGK 2
flash_point_f
122.0 °F
flash_point_c
50 °C
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Stana Kovačević et al.
Polymers, 11(5) (2019-05-30)
The objective of this research was to verify the feasibility of the use of newly synthesized biopolymer materials for sizing cotton yarns based on the basic principles of chemical modification. Research included acid hydrolysis of potato starch up to controlled
Wenwen Li et al.
Macromolecular rapid communications, 32(1), 74-81 (2011-03-25)
Amphiphilic star shaped polymers with poly(ethylene oxide) (PEO) arms and cross-linked hydrophobic core were synthesized in water via either conventional free radical polymerization (FRP) or atom transfer radical polymerization (ATRP) techniques using a simple "arm-first" method. In FRP, PEO based
Lianghui Liu et al.
Organic letters, 14(22), 5692-5695 (2012-10-31)
In the presence of a catalytic amount of radical initiator AIBN, primary amines are oxidatively coupled to imines and tertiary amines are cyanated to α-aminonitriles. These "metal-free" aerobic oxidative coupling reactions may find applications in a wide range of "green"
Idil Ipek Yilmaz et al.
Macromolecular rapid communications, 33(9), 856-862 (2012-04-21)
Polymers containing maleimide groups on their side chains have been synthesized by utilization of a novel styrenic monomer containing a masked-maleimide unit. AIBN initiated free radical polymerization and reverse addition-fragmentation chain transfer (RAFT) polymerization was utilized for synthesis of copolymers
Mathieu Le Noir et al.
Journal of separation science, 32(9), 1471-1479 (2009-04-29)
Highly efficient removal of endocrine-disrupting compounds (EDCs) such as 17beta-estradiol (E2), 4-nonylphenol (NP) and atrazine from water was achieved using a novel macroporous adsorption medium. The medium consisted of a macroporous poly(vinyl alcohol) (PVA) cryogel with molecularly imprinted polymer (MIP)
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