248401
Magnesium methyl carbonate solution
2.0 M in DMF
Synonym(s):
MMC, Methoxymagnesium methyl carbonate, Methyl methoxymagnesium carbonate, Stile’s reagent
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About This Item
Linear Formula:
CH3OMgOCO2CH3
CAS Number:
Molecular Weight:
130.38
UNSPSC Code:
12352302
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4342967
Form:
liquid
form
liquid
Quality Level
concentration
2.0 M in DMF
density
1.103 g/mL at 25 °C
SMILES string
CO[Mg]OC(=O)OC
InChI
1S/C2H4O3.CH3O.Mg/c1-5-2(3)4;1-2;/h1H3,(H,3,4);1H3;/q;-1;+2/p-1
InChI key
PNVKCUSCADAAMP-UHFFFAOYSA-M
General description
Magnesium methyl carbonate is also known as Stile′s reagent. It is used as a carboxylating agent for the α-carboxylation of nitroalkanes, ketones, lactones, hydantoins, and phenols.
signalword
Danger-Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2
Storage Class
3 - Flammable liquids
wgk
WGK 3
flash_point_f
136.4 °F - closed cup
flash_point_c
58 °C - closed cup
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Chen Ling et al.
Cell discovery, 2, 16047-16047 (2017-01-07)
The recruitment of FANCM, a conserved DNA translocase and key component of several DNA repair protein complexes, to replication forks stalled by DNA interstrand crosslinks (ICLs) is a step upstream of the Fanconi anemia (FA) repair and replication traverse pathways
Mara Colombo et al.
Human mutation, 39(5), 729-741 (2018-02-21)
Although the spliceogenic nature of the BRCA2 c.68-7T > A variant has been demonstrated, its association with cancer risk remains controversial. In this study, we accurately quantified by real-time PCR and digital PCR (dPCR), the BRCA2 isoforms retaining or missing exon 3.
Akbar Adjie Pratama et al.
Scientific reports, 7(1), 9156-9156 (2017-08-24)
Bacteriophages constitute key gene transfer agents in many bacteria. Specifically, they may confer gene mobility to Paraburkholderia spp. that dwells in soil and the mycosphere. In this study, we first screened mycosphere and bulk soils for phages able to produce