577766
Molybdenum hexacarbonyl
≥99.9% trace metals basis (excluding W) purified by sublimation
Synonym(s):
Molybdenumhexacarbonyl, Hexacarbonylmolybdenum(0)
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About This Item
Linear Formula:
Mo(CO)6
CAS Number:
Molecular Weight:
264.00
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
237-713-3
MDL number:
vapor density
9.1 (vs air)
assay
≥99.9% trace metals basis
form
solid
purified by
sublimation
reaction suitability
core: molybdenum, reagent type: catalyst
bp
156 °C (lit.)
mp
150 °C (dec.) (lit.)
density
1.96 g/mL at 25 °C (lit.)
SMILES string
[Mo].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
InChI
1S/6CO.Mo/c6*1-2;
InChI key
KMKBZNSIJQWHJA-UHFFFAOYSA-N
General description
Atomic number of base material: 42 Molybdenum
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signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation
Storage Class
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
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Paul Nissenson et al.
Physical chemistry chemical physics : PCCP, 8(40), 4700-4710 (2006-10-19)
While there is increasing evidence for unique chemical reactions at interfaces, there are fewer data on photochemistry at liquid-vapor junctions. This paper reports a comparison of the photolysis of molybdenum hexacarbonyl, Mo(CO)(6), in 1-decene either as liquid droplets or in
John Spencer
Future medicinal chemistry, 2(2), 161-168 (2011-03-24)
Microwave-mediated chemistry, involving the reduction of nitroarenes with molybdenum hexacarbonyl as a stoichiometric reducing agent, has been employed in the synthesis of a range of anilines. Many of these reactions exhibit high levels of chemoselectivity, tolerating unsaturation, steric hindrance and
Qingxi Meng et al.
Journal of molecular modeling, 18(8), 3489-3499 (2012-02-03)
Density functional theory (DFT) was used to investigate the Mo-catalyzed intramolecular Pauson-Khand reaction of 3-allyloxy-1-propynylphosphonates. All intermediates and transition states were optimized completely at the B3LYP/6-31 G(d,p) level [LANL2DZ(f) for Mo]. In the Mo-catalyzed intramolecular Pauson-Khand reaction, the C–C oxidative