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Merck

77450

2-Bromoacetophenone

derivatization grade (GC derivatization), LiChropur™, ≥99.0%

Synonym(s):

ω-Bromoacetophenone, Phenacyl bromide

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About This Item

Linear Formula:
C6H5COCH2Br
CAS Number:
70-11-1
Molecular Weight:
199.04
UNSPSC Code:
23151817
NACRES:
NA.22
PubChem Substance ID:
329767691
EC Number:
200-724-9
Beilstein/REAXYS Number:
606474
MDL number:
MFCD00000195
Assay:
≥99.0% (GC), ≥99.0%
Form:
crystals

Key Documents

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InChI key

LIGACIXOYTUXAW-UHFFFAOYSA-N

InChI

1S/C8H7BrO/c9-6-8(10)7-4-2-1-3-5-7/h1-5H,6H2

SMILES string

BrCC(=O)c1ccccc1

grade

derivatization grade (GC derivatization)

assay

≥99.0% (GC), ≥99.0%

form

crystals

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Acylations

technique(s)

gas chromatography (GC): suitable

bp

135 °C/18 mmHg (lit.)

mp

48-51 °C (lit.), 49-50 °C

storage temp.

2-8°C

Quality Level

100

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General description

2-Bromoacetophenone is a commonly used derivatization agent for fatty acid detection in biological samples.

Application

Preparation of crystalline esters from acids

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

pictograms

CorrosionExclamation mark
GHS05,GHS07

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1

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Certificates of Analysis (COA)

Lot/Batch Number
BCCG1542
BCBG9218V

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High-performance liquid chromatography of fatty acids in biological samples.
Lima ES and Abdalla DSP
Analytica Chimica Acta, 465(1-2), 81-91 (2002)
A Kanstrup et al.
Archives of biochemistry and biophysics, 304(2), 332-337 (1993-08-01)
A series of 18 phenacyl bromide and iodoacetamide analogues have been synthesized and used to alkylate Met-398 situated in the S'1 binding site of carboxypeptidase Y. The course of the reactions was monitored by measurements of the peptidase and esterase
S Ramalingam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 78(2), 826-834 (2011-01-11)
In this work, the experimental and theoretical spectra of 4-chloro-2-bromoacetophenone (4C2BAP) are studied. FT-IR and FT-Raman spectra of title molecule have been recorded in the region 4000-100 cm(-1). The structural and spectroscopic data of the molecule in the ground state
P A Wender et al.
Organic letters, 1(13), 2117-2120 (2000-06-03)
[formula: see text] 4'-Bromoacetophenone derivatives which upon excitation can generate monophenyl radicals capable of hydrogen atom abstraction were investigated as photoinducible DNA cleaving agents. Pyrrolecarboxamide-conjugated 4'-bromoacetophenones were synthesized, and their DNA cleaving activities and sequence selectivities were determined.
Anabha E Raveendran et al.
Organic & biomolecular chemistry, 8(4), 901-905 (2010-02-06)
Nucleophilic heterocyclic carbenes (NHCs) have been used for the first time as catalysts in the cyclopropanation of ethyl cyanocinnamates with phenacyl bromide by Michael-initiated ring-closure (MIRC).
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