235202
4-Bromomethyl-7-methoxycoumarin
97%
Synonym(s):
BMC, Br-Mmc
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About This Item
Empirical Formula (Hill Notation):
C11H9BrO3
CAS Number:
Molecular Weight:
269.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-448-3
Beilstein/REAXYS Number:
187211
MDL number:
Assay:
97%
Form:
solid
Quality Segment
assay
97%
form
solid
mp
213-215 °C (lit.)
solubility
chloroform: soluble 20 mg/mL, clear, colorless to faintly yellow
fluorescence
λex 322 nm; λem 395 nm (after derivatization)
functional group
bromo, ester
SMILES string
COc1ccc2C(CBr)=CC(=O)Oc2c1
InChI
1S/C11H9BrO3/c1-14-8-2-3-9-7(6-12)4-11(13)15-10(9)5-8/h2-5H,6H2,1H3
InChI key
CTENSLORRMFPDH-UHFFFAOYSA-N
Application
4-Bromomethyl-7-methoxycoumarin has been used:
- as derivatization reagent in determination of 5-fluorouracil (5-FU) in human plasma by HPLC-tandem mass spectrometry
- as derivatization reagent in fluorescence detection of sodium monofluoroacetate (MFA-Na) in biological samples by HPLC
- in the synthesis of new caged derivatives of hydrolysis-resistant 8-bromoadenosine cyclic 3′,5′-monophosphate (8-Br-cAMP) and 8-bromoguanosine cyclic 3′,5′-monophosphate (8-Br-cGMP)
- in TLC and HPLC separation and fluorometric analysis of a wide range of naturally occurring acids, including bile and thromboxane B2
Fluorescent label for fatty acids.
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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