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300977

(R)-4-Benzyl-2-oxazolidinone

Name: (<I>R</I>)-4-Benzyl-2-oxazolidinone
Brand: ALDRICH

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₁NO₂

CAS Number:

102029-44-7

Molecular Weight:

177.20

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24858151

MDL number:

MFCD00010846

Beilstein/REAXYS Number:

4782551

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Properties

Quality Segment

100

assay

99%

form

powder

optical activity

[α]18/D +64°, c = 1 in chloroform

mp

88-90 °C

SMILES string

O=C1N[C@@H](CO1)Cc2ccccc2

InChI

1S/C10H11NO2/c12-10-11-9(7-13-10)6-8-4-2-1-3-5-8/h1-5,9H,6-7H2,(H,11,12)/t9-/m1/s1

InChI key

OJOFMLDBXPDXLQ-SECBINFHSA-N

Description

Application

(R)-4-Benzyl-2-oxazolidinone may be used as a starting material in the synthesis of enantiopure carbocyclic nucleosides. It may also be used as a chiral auxiliary in the enantioselective synthesis of (2R,2′S)-erythro-methylphenidate.

Versatile chiral auxiliary for asymmetric synthesis. For a recent review, see Aldrichimica Acta.

Used in the synthesis of HIV protease inhibitors.

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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