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651745

Copper(I) chloride

AnhydroBeads™, ≥99.99% trace metals basis

Synonym(s):

Copper monochloride, Cuprous chloride

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About This Item

Linear Formula:
CuCl
CAS Number:
7758-89-6
Molecular Weight:
99.00
NACRES:
NA.23
PubChem Substance ID:
24883859
UNSPSC Code:
12352302
EC Number:
231-842-9
MDL number:
MFCD00010971
Assay:
≥99.99% trace metals basis
Grade:
synthesis grade
Solubility:
slightly soluble 0.47 g/L at 20 °C
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grade

synthesis grade

vapor pressure

1.3 mmHg ( 546 °C)

product line

AnhydroBeads™

assay

≥99.99% trace metals basis

reaction suitability

core: copper, reagent type: catalyst

impurities

≤100.0 ppm Trace Metal Analysis

bp

1490 °C (lit.)

mp

430 °C (lit.)

solubility

slightly soluble 0.47 g/L at 20 °C

application(s)

electroplating
material synthesis precursor

SMILES string

Cl[Cu]

InChI

1S/ClH.Cu/h1H;/q;+1/p-1

InChI key

OXBLHERUFWYNTN-UHFFFAOYSA-M

General description

The structure of copper(I) chloride is similar to zinc-blende crystal at room temperature, at 407 °C the structure is wurtzite and at still higher temperature it forms copper(I) chloride vapor as determined by mass spectroscopy.

Application

CuCl may be used as an initiator for hydrostannation of α,β-unsaturated ketones and other similar radical reactions.
Shows unique character as an initiator of radical reactions such as the hydrostannation of α,β-unsaturated ketones.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
0000285899
0000285898
0000278709
0000285899
0000285898

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Chethana Gadiyar et al.
Chemical science, 9(25), 5658-5665 (2018-08-01)
Nanocrystal-seeded synthesis relies on the reaction of nanocrystal seeds with a molecular precursor and it can be regarded as the link between sol-gel and solid-state chemistries. This synthesis approach aims at accessing compositionally complex materials, yet to date its full
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