731277
2-Cyano-2-propyl 4-cyanobenzodithioate
98% (HPLC)
Synonym(s):
2-Cyanoprop-2-yl 4-cyanodithiobenzoate, 4-Cyanobenzenecarbodithioic acid 1-cyano-1-methylethyl ester
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About This Item
Empirical Formula (Hill Notation):
C12H10N2S2
CAS Number:
Molecular Weight:
246.35
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Quality Level
assay
98% (HPLC)
form
solid
mp
122-127 °C
SMILES string
CC(C)(SC(=S)c1ccc(cc1)C#N)C#N
InChI
1S/C12H10N2S2/c1-12(2,8-14)16-11(15)10-5-3-9(7-13)4-6-10/h3-6H,1-2H3
InChI key
GLQSCQVGVPUIPC-UHFFFAOYSA-N
General description
Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.
Application
RAFT agent for controlled radical polymerization; especially suited for the polymerization of methyl methacrylate and styrene monomers. Chain Transfer Agent (CTA)
Legal Information
Sold for research purposes only: See sigma-aldrich.com/raftlicense. Patents: WO98/01478; WO99/311444.
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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being