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857300

(1R)-(+)-Camphor

Name: (1<I>R</I>)-(+)-Camphor
Brand: ALDRICH

98%

Synonym(s):

(+)-Camphor, (1R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):

C₁₀H₁₆O

CAS Number:

464-49-3

Molecular Weight:

152.23

UNSPSC Code:

12352115

NACRES:

NA.22

PubChem Substance ID:

24888438

EC Number:

207-355-2

Beilstein/REAXYS Number:

2042745

MDL number:

MFCD00064149

Assay:

98%

Form:

powder

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Properties

vapor density

5.24 (vs air)

Quality Segment

200

vapor pressure

4 mmHg ( 70 °C)

assay

98%

form

powder

optical activity

[α]25/D +44.1°, c = 10 in ethanol

autoignition temp.

870 °F

expl. lim.

3.5 %

mp

179-181 °C (lit.)

functional group

ketone

SMILES string

C[C@@]1(CC2)C(C)(C)[C@H]2CC1=O

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

Description

Application

Chiral intermediate and auxiliary.

(1R)-(+)-Camphor has been used as a standard during the enantioselective gas chromatography-mass spectrometry (GC-MS) analysis of the constituents of Achillea ligustica essential oil.
It may also be used to synthesize:

{N,N′-bis[(1R,2R,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]-1,2-ethanediamine}, a C2-symmetrical diamine
chiral oxazaborolidines
(-)-(1R,2R)-1,2-dihydroxy-3,3-dimethylnorbornane

pictograms

GHS02,GHS08,GHS05,GHS07

signalword

Danger

hcodes

H228,H315,H318,H332,H371

pcodes

P210 - P280 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338 - P308 + P311

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

target_organs

Lungs

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 1

flash_point_f

147.2 °F - closed cup

flash_point_c

64 °C - closed cup

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

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