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Merck

679186

Acetonitrile solution

suitable for HPLC, contains 5 % (v/v) water, 0.1 % (v/v) formic acid, 0.05 % (w/v) ammonium formate

Synonym(s):

ACN, Cyanomethane, Ethyl nitrile, Methyl cyanide

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About This Item

Linear Formula:
CH3CN
CAS Number:
Molecular Weight:
41.05
UNSPSC Code:
12190000
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4124158
grade:
HPLC grade
technique(s):
HPLC: suitable
bp:
81-82 °C (lit.)
vapor pressure:
72.8 mmHg

Product Name

Acetonitrile solution, contains 0.05 % (w/v) ammonium formate, 5 % (v/v) water, 0.1 % (v/v) formic acid, suitable for HPLC

SMILES string

CC#N

InChI key

WEVYAHXRMPXWCK-UHFFFAOYSA-N

InChI

1S/C2H3N/c1-2-3/h1H3

grade

HPLC grade

vapor density

1.41 (vs air)

vapor pressure

72.8 mmHg

form

liquid

contains

0.05 % (w/v) ammonium formate
0.1 % (v/v) formic acid
5 % (v/v) water

expl. lim.

8 % (lit.)

technique(s)

HPLC: suitable

bp

81-82 °C (lit.)

mp

-48 °C (lit.)

density

0.782 g/mL at 25 °C
0.807 g/mL at 25 °C

format

mixture

Quality Level

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Application


  • Detection of Amino Acids via Chemiluminescence: Acetonitrile is employed in the detection of α-amino acids using peroxyoxalate chemiluminescence. A study demonstrated the use of a mixed solution of water, acetonitrile, and ethyl acetate for detecting amino acids, highlighting its efficacy in analytical applications. This method enhances the sensitivity and accuracy of amino acid detection, making it crucial for biochemical and clinical analyses (Kan et al., American Journal of Analytical Chemistry, 2020).

  • Redox Properties of N-Hydroxyimides: Acetonitrile mixed with sulfuric acid is used to study the redox properties of N-hydroxyimides, acting as a hydrogen atom transfer (HAT) mediator for alcohol oxidation. This application is significant in understanding the electrochemical behavior of organic compounds and developing new catalytic processes for oxidation reactions (Kishioka, Journal of Electroanalytical Chemistry, 2023).

  • Electrode Reactions in Catalytic Mediation: Acetonitrile solution is used in investigating the electrode reactions of N-hydroxyphthalimide in sulfuric acid. This study focuses on its role as a catalytic mediator for alcohol oxidation, providing insights into the electrochemical mechanisms involved. The findings contribute to the development of efficient catalytic systems for organic transformations (Kishioka, Journal of Electroanalytical Chemistry, 2022).

  • Excitation of Europium Complexes: Acetonitrile solution is utilized in the interaction of Eu(FOD)3 with xenon difluoride to study ligand-assisted excitation of Eu(III). This research explores the photophysical properties of europium complexes, which are essential for developing luminescent materials for various applications, including lighting and display technologies (Masyagutova et al., Journal of Fluorine Chemistry, 2024).


General description

LC/MS suitability tested

Other Notes

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Packaging

M-Bottle for Solvents
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Preparation Note

Product filtered through a 0.2 μm filter

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk

WGK 2

flash_point_f

36.0 °F - closed cup

flash_point_c

2.22 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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