404985
Titanium(IV) chloride solution
0.09 M in 20% HCl
Synonym(s):
Titanium tetrachloride
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About This Item
Linear Formula:
TiCl4
CAS Number:
Molecular Weight:
189.68
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352300
MDL number:
Form:
liquid
form
liquid
Quality Level
reaction suitability
reagent type: catalyst
core: titanium
concentration
0.09 M in 20% HCl
density
1.099 g/mL at 25 °C
SMILES string
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI key
XJDNKRIXUMDJCW-UHFFFAOYSA-J
Application
Reagent for the detection of peroxides in ethyl ether. Activates pyrrolidines for improved conversion, via a modified Bouveault reaction, to the corresponding α,α-dimethylamines.
Titanium(IV) chloride (TiCl4) solution may be used to synthesize nanosized titanium dioxide and nano/micro-sized titania powders.
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
8B - Non-combustible corrosive hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
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Reagent Chemicals (1992)
Influence of solution concentration on the hydrothermal preparation of titania crystallites.
Yanqing Z, et al.
Journal of Materials Chemistry, 11(5), 1547-1551 (2001)
Titanium tetrachloride promoted hydrolysis of cephalosporin tert-butyl esters.
Valencic M, et al.
Tetrahedron Letters, 39(12), 1625-1628 (1998)