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Merck

115169

Tetramethylthiourea

98%

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About This Item

Linear Formula:
(CH3)2NCSN(CH3)2
CAS Number:
Molecular Weight:
132.23
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
220-488-0
Beilstein/REAXYS Number:
1744916
MDL number:
Assay:
98%
Form:
solid
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Product Name

Tetramethylthiourea, 98%

InChI key

MNOILHPDHOHILI-UHFFFAOYSA-N

InChI

1S/C5H12N2S/c1-6(2)5(8)7(3)4/h1-4H3

SMILES string

CN(C)C(=S)N(C)C

assay

98%

form

solid

bp

245 °C (lit.)

mp

75-77 °C (lit.)

storage temp.

2-8°C

Quality Level

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Application

Tetramethylthiourea forms BF3 adduct with tetramethylselenourea.

General description

Tetramethylthiourea molecule shows crystallographic two-fold symmetry with weak hydrogen bond packing, which connects the molecules to form layers.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Jin Dai et al.
American journal of respiratory cell and molecular biology, 29(3 Pt 1), 352-358 (2003-03-22)
There is evidence that chronic exposure to high levels of ambient particulate pollutants (PM) is associated with chronic airflow obstruction, but how this occurs is not known. We exposed rat tracheal explants to Ottawa urban air particles (ECH93) or diesel
Peter G Jones et al.
Acta crystallographica Section B, Structural science, crystal engineering and materials, 69(Pt 4), 405-413 (2013-07-23)
We have redetermined the known structures of (i) methylthiourea (MTU) and (ii) 1,1-dimethylthiourea (1,1-DMTU), and investigated the structure of 1,3-dimethylthiourea (1,3-DMTU), which was however severely disordered. We report the structures of crystalline adducts of (iii) MTU with morpholine (1:1), (iv)
J Palassis
American Industrial Hygiene Association journal, 41(2), 91-97 (1980-02-01)
Tetramethyl and ethylene thiourea are collected from air using midget impingers containing 15 mL water. Ethylene thiourea may also be collected from air using PVC or cellulose ester membrane filters which are then extracted with water. Pentacyanoamineferrate reagent is added
Urea-boron trihalide adducts. IV. Ionic-covalent equilibria in the tetramethylthiourea-BF3 and tetramethylselenourea-BF3 systems and the influence of B2F7-formation.
Hartman JS, et al.
Canadian Journal of Chemistry, 54(7), 1121-1129 (1976)
J Bouvet et al.
International journal of developmental neuroscience : the official journal of the International Society for Developmental Neuroscience, 5(4), 345-355 (1987-01-01)
A morphometric analysis of Purkinje cells in the developing cerebellar cortex of the chick was performed in normal animals and embryos made hypothyroid by one or two spaced injections of tetramethylthiourea. Profiles of 162 Purkinje cells, from Golgi-Cox treated sections

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