137995
1,2,3-Trimethoxybenzene
98%
Synonym(s):
Pyrogallol trimethyl ether
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About This Item
Linear Formula:
C6H3(OCH3)3
CAS Number:
Molecular Weight:
168.19
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-207-2
Beilstein/REAXYS Number:
1910422
MDL number:
Product Name
1,2,3-Trimethoxybenzene, 98%
InChI key
CRUILBNAQILVHZ-UHFFFAOYSA-N
InChI
1S/C9H12O3/c1-10-7-5-4-6-8(11-2)9(7)12-3/h4-6H,1-3H3
SMILES string
COc1cccc(OC)c1OC
assay
98%
form
chunks
bp
241 °C (lit.)
mp
43-47 °C (lit.)
density
1.112 g/mL at 25 °C (lit.)
Quality Level
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Application
1,2,3-Trimethoxybenzene was used to study the effect of solvent on photoinduced electron-transfer reactions.
General description
1,2,3-Trimethoxybenzene on condensation with 2,4-diamino-5-(hydroxymethyl)pyrimidine yields 2,4-diamino-5-(2,3,4-trimethoxybenzyl)pyrimidine.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
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Zhangjie Shi et al.
Journal of the American Chemical Society, 126(19), 5964-5965 (2004-05-13)
A gold-catalyzed cyclialkylation of electron-rich arenes with tethered epoxides afforded 3-chromanols stereospecifically.
Romelo Gibe et al.
Chemical communications (Cambridge, England), (14)(14), 1550-1551 (2002-08-23)
Nicholas reactions of the p-phenyl linked bis(propargyl acetate) complex (3a) with electron rich arenes give cyclophanetetrayne complexes (5). The use of bis(propargyl ether) complex (8) with (3a) allows formation of a mixed cyclophanetetrayne complex (9), and in addition gives retro-Nicholas/intramolecular
A Stuart et al.
Journal of medicinal chemistry, 26(5), 667-673 (1983-05-01)
A new route to 2,4-diamino-5-(4-hydroxybenzyl)pyrimidines has been developed that involves the condensation of 2,4-diamino-5-(hydroxymethyl)pyrimidine with phenols in acidic medium. The use of phenol and its 2,6-dialkyl derivatives produces 5-(4-hydroxybenzyl)pyrimidines exclusively. However, 2,6-dimethoxyphenol produces a mixture of 5-(3-hydroxy-2,4-dimethoxybenzyl)- and 5-(4-hydroxy-3,5-dimethoxybenzyl)pyrimidines. The
Jian Zhi Hu et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 198(1), 105-110 (2009-02-28)
An isotropic-anisotropic shift 2D correlation spectroscopy is introduced that combines the advantages of both magic angle turning (MAT) and magic angle hopping (MAH) technologies. In this new approach, denoted DMAT for "discrete magic angle turning", the sample rotates clockwise followed
Solvent effects on photoinduced electron-transfer reactions.
Niwa T, et al.
The Journal of Physical Chemistry, 97(46), 11960-11964 (1993)
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