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Merck

216194

Hydrazine monohydrochloride

97%

Synonym(s):

Hydrazinium chloride, Hydrazinium monochloride

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About This Item

Linear Formula:
NH2NH2 · HCl
CAS Number:
2644-70-4
Molecular Weight:
68.51
NACRES:
NA.22
PubChem Substance ID:
24852940
UNSPSC Code:
12352100
EC Number:
220-154-4
MDL number:
MFCD00044368
Assay:
97%
Form:
solid

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InChI key

BIVUUOPIAYRCAP-UHFFFAOYSA-N

InChI

1S/ClH.H4N2/c;1-2/h1H;1-2H2

SMILES string

Cl[H].NN

assay

97%

form

solid

mp

89 °C (lit.)

functional group

hydrazine

Quality Level

200

Related Categories

General description

Hydrazine monohydrochloride is commonly used as a reagent in the synthesis of pyrazoles.

Application

Hydrazine monohydrochloride has been used:
  • as catalyst in the synthesis of titanium oxide polymers via catalytic sol-gel process
  • in fabrication of amorphous titanium dioxide (TiO2) thin films exhibiting high refractive indices and high transparency
  • in preparation of ethyl 3-ethoxy-1H-pyrazole-4-carboxylate

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificates of Analysis (COA)

Lot/Batch Number
WXBF6289V
WXBF4988V
WXBF2224V
WXBD8386V
MKCQ5808

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Ahmed M Elbedwehy et al.
Polymers, 11(12) (2019-11-30)
Super adsorbent polymers can be considered to be a very efficient solution for wastewater treatment. In general, their adsorption capacities depend on the type and amount of the functional groups present on the surface of the polymers, while their economic
Sandrine Guillou et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(15), 4669-4677 (2010-03-25)
Our program, which has focused on the preparation of new pyrazole derivatives, has led us to report here an original and simplified preparation of ethyl 3-ethoxy-1H-pyrazole-4-carboxylate. This is based on the reaction of hydrazine monohydrochloride and diethyl 2-(ethoxymethylene)malonate. Further transformations
Tomáš Taubner et al.
International journal of biological macromolecules, 103, 202-207 (2017-05-21)
Alginic acid is a suitable material for modification to prepare new derivatives because of presence of its carboxyl groups. The high content of carboxyl groups over the entire length of its chain renders it an easily modifiable material with a
An efficient synthesis of substituted pyrazoles from one-pot reaction of ketones, aldehydes, and hydrazine monohydrochloride
V Lellek, et al.
Synlett, 29, 1071-1075 (2018)
Wataru Shimizu et al.
Journal of nanoscience and nanotechnology, 12(5), 3732-3738 (2012-08-03)
Titanium oxide polymers having a low-fractal dimension (d(f) < 2) were rapidly synthesized from titanium tetra-n-butoxide via a catalytic sol-gel process with a hydrazine monohydrochloride catalyst. Different from conventional sol-gel processes aimed at producing low-fractal dimension titanium oxide polymers, the
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