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Merck

295590

Nitrous oxide

99%

Synonym(s):

Dinitrogen monoxide, Laughing gas

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About This Item

Empirical Formula (Hill Notation):
N2O
CAS Number:
Molecular Weight:
44.01
UNSPSC Code:
12142100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
233-032-0
Beilstein/REAXYS Number:
8137358
MDL number:
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Product Name

Nitrous oxide, 99%

InChI key

GQPLMRYTRLFLPF-UHFFFAOYSA-N

InChI

1S/N2O/c1-2-3

SMILES string

[O-][N+]#N

vapor density

1.53 (15 °C, vs air)

vapor pressure

51.7 mmHg ( 21 °C)

assay

99%

bp

−88 °C (lit.)

mp

−91 °C (lit.)

Quality Level

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Application

  • Nitrous oxide allows selective oxygen atom transfer reactions while minimizing the risk of over-oxidation. Therefore, it is used to oxidize disilenes, silanimines, silaethenes and silylenes.
  • Along with Ru-porphyrin catalyst, it can be used in the epoxidation of olefins and steroids.
  • It can be used as an oxidant in for the metal-catalyzed oxidative homo- and cross-coupling of Grignard reagents.
  • N2O can also be used as a nitrogen-dopant source to synthesize p-type zinc oxide nanowires (ZnO NWs) via vapor-liquid-solid growth.

Other Notes

Packaging

Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.

Compatible with the following:
  • Aldrich® lecture-bottle station systems
  • Aldrich® lecture-bottle gas regulators

Legal Information

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Ox. Gas 1 - Press. Gas Liquefied gas - STOT SE 3

target_organs

Central nervous system

Storage Class

2A - Gases

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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Oxidative Coupling Reactions of Grignard Reagents with Nitrous Oxide.
Kiefer G, et al.
Angewandte Chemie (International Edition in English), 52(24), 6302-6305 (2013)
p-type ZnO nanowire arrays.
Yuan G D, et al.
Nano Letters, 8(8), 2591-2597 (2008)
Synthetic chemistry with nitrous oxide.
Severin K.
Chemical Society Reviews, 44(17), 6375-6386 (2015)
Imke Kuiper et al.
Global change biology, 19(9), 2814-2825 (2013-04-30)
Nitrous oxide (N2 O) emissions from soils contribute significantly to global warming. Mitigation of N2 O emissions is severely hampered by a lack of understanding of its main controls. Fluxes can only partly be predicted from soil abiotic factors and
R L M Schils et al.
Animal : an international journal of animal bioscience, 7 Suppl 1, 29-40 (2012-10-04)
Herbivores are a significant source of nitrous oxide (N(2)O) emissions. They account for a large share of manure-related N(2)O emissions, as well as soil-related N(2)O emissions through the use of grazing land, and land for feed and forage production. It

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