298212
Copper(I) thiocyanate
99%
Synonym(s):
Cuprous thiocyanate
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About This Item
Linear Formula:
CuSCN
CAS Number:
Molecular Weight:
121.63
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
214-183-1
MDL number:
Assay:
99%
Form:
powder
Product Name
Copper(I) thiocyanate, 99%
InChI key
PDZKZMQQDCHTNF-UHFFFAOYSA-M
InChI
1S/CHNS.Cu/c2-1-3;/h3H;/q;+1/p-1
SMILES string
[Cu]SC#N
assay
99%
form
powder
reaction suitability
core: copper
Quality Level
Related Categories
Application
The product can be prepared from Cu(CH3COO)2·H2O, AgNO3, NH4NCS and im(im = imidazole). The structure and optical properties were reported. It is an air- and light-stable source of Cu(I).
General description
The crystal belongs to the orthorhombic system, space group: Pbca,a=10.994(9)Å, b=7.224(3)Å,c=6.662(2)Å.
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
supp_hazards
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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The crystal structure of copper(I) thiocyanate and its relation to the crystal structure of copper(II) diammine dithiocyanate complex
Kabesova M, et al.
Inorgorganica Chimica Acta, 17, 161-165 (1976)
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), 41(25), 7513-7525 (2012-05-24)
A number of adducts of copper(I) thiocyanate with bulky tertiary phosphine ligands, and some nitrogen-base solvates, were synthesized and structurally and spectroscopically characterised. CuSCN:PCy3 (1:2), as crystallized from pyridine, is shown by a single crystal X-ray study to be a
Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound
Bie HY, et al.
Journal of Molecular Structure, 660, 107-112 (2003)
K Luey et al.
The New Zealand medical journal, 93(676), 36-38 (1981-01-28)
Faecal fat excretion was estimated in 24 patients using three methods. Quantitative estimations of fat excretion were calculated from both a three day faecal fat collection and a twenty-four hour faecal collection corrected for excretion of a cuprous thiocyanate marker.
Graham A Bowmaker et al.
Dalton transactions (Cambridge, England : 2003), (39)(39), 5290-5292 (2008-10-02)
The role of short-range diffusion in solvent-assisted mechanochemical synthesis is demonstrated in studies of a polymorphic transition and a ligand dissociation reaction involving copper(I) thiocyanate complexes.
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