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Merck

323446

Ammonium tetrathiomolybdate

99.97% trace metals basis

Synonym(s):

Ammonium thiomolybdate, Diammonium tetrathiomolybdate

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About This Item

Linear Formula:
(NH4)2MoS4
CAS Number:
15060-55-6
Molecular Weight:
260.28
NACRES:
NA.23
PubChem Substance ID:
24859366
UNSPSC Code:
12352302
MDL number:
MFCD00136013
assay:
99.97% trace metals basis
form:
crystalline

Product Name

Ammonium tetrathiomolybdate, 99.97% trace metals basis

InChI

1S/Mo.2H3N.4S/h;2*1H3;;;;/q;;;;;2*-1/p+2

SMILES string

[NH4+].[NH4+].[S-][Mo]([S-])(=S)=S

InChI key

PQNOIAHNKHBLRN-UHFFFAOYSA-P

assay

99.97% trace metals basis

form

crystalline

reaction suitability

reagent type: catalyst

impurities

≤350.0 ppm Trace Metal Analysis

mp

>300 °C (lit.)

Quality Level

100

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Application

Ring opening of aziridines leading to sulfides and disulfides.
This classic building block for transition metal sulfide cluster compounds was recently used in a low-temperature, solid state synthesis of a new series of heterometallic sulfide clusters stabilized with dppm [bis(diphenylphosphino)methane] ligands.

Biochem/physiol Actions

Acts as a chelator in vivo to reduce copper levels. Tetrathiomolybdate interferes with angiogenesis and reduces tumor growth. Its mechanism may involve inhibition of NF-κB and downstream cytokines.

Storage Class

13 - Non Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCX6606
0000269337
0000269337
MKCV2919
MKCR6910

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Pengfei Cao et al.
Scientific reports, 7(1), 16048-16048 (2017-11-24)
Amorphous molybdenum sulfide/carbon black (MoS
Yu Cheng et al.
Molecular pharmaceutics, 16(8), 3489-3501 (2019-06-28)
Recently, multifunctional clearable inorganic theranostic nanoparticles have been attracting more and more attention. Protein-based nanoparticles can be cleared by the hepatobiliary system efficiently. In this work, ultrasmall gadolinium oxide (Gd2O3) nanoparticles, which possess the advantage of high longitudinal relaxation rate
Devarajulu Sureshkumar et al.
The Journal of organic chemistry, 72(6), 2106-2117 (2007-02-24)
A comprehensive study of a general and effective one-step procedure for the synthesis of beta-sulfonamidodisulfides directly from N-tosyl aziridines in a regio- and stereospecific manner under neutral conditions without the use of any Lewis acid or base has been reported.
Satoru Yamasaki et al.
The Journal of cell biology, 177(4), 637-645 (2007-05-16)
Zinc is an essential trace element required for enzymatic activity and for maintaining the conformation of many transcription factors; thus, zinc homeostasis is tightly regulated. Although zinc affects several signaling molecules and may act as a neurotransmitter, it remains unknown
Yu Lei et al.
Science advances, 6(32), eabc4250-eabc4250 (2020-08-22)
Two-dimensional transition metal dichalcogenides (TMDs) emerged as a promising platform to construct sensitive biosensors. We report an ultrasensitive electrochemical dopamine sensor based on manganese-doped MoS2 synthesized via a scalable two-step approach (with Mn ~2.15 atomic %). Selective dopamine detection is
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