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Merck

345164

Tin(II) acetate

solid

Synonym(s):

Stannous acetate, Tin acetate, Tin diacetate

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About This Item

Linear Formula:
Sn(CH3CO2)2
CAS Number:
Molecular Weight:
236.80
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
211-335-9
MDL number:

Product Name

Tin(II) acetate,

InChI key

PNOXNTGLSKTMQO-UHFFFAOYSA-L

InChI

1S/2C2H4O2.Sn/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2

SMILES string

CC(=O)O[SnH2]OC(C)=O

form

solid

reaction suitability

core: tin
reagent type: catalyst

mp

180-182 °C (lit.)

Quality Level

Application

  • Enhances the rate of thermal depolymerization of poly(lactic acid) fibers
  • Reactant for the synthesis of Sn-Cu bimetallic nanoparticles
  • used in in preparation of tin anode by organic electroplating for rechargeable thin-film batteries
  • Used as tin source for preparation of high surface area tin oxide catalysts
Used to prepare tin(IV) oxide thin films by photochemical vapor deposition. With palladium(II) acetate, an efficient catalytic system for C-H activation of the methoxy group of anisole.

General description

Tin(II) acetate can be used as a photocatalyst to produce Arylstannane(IV) Reagents.

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Photocatalytic Reaction of Aryl Halides with Tin (II) Acetate to Generate Arylstannane (IV) Reagents
Zemtsov AA, et al.
ACS Catalysis, 13, 12766-12773 (2023)
Keiko Yakabi et al.
ChemSusChem, 10(18), 3652-3659 (2017-08-15)
The Baeyer-Villiger oxidation is a key transformation for sustainable chemical synthesis, especially when H
The Journal of Organic Chemistry, 59, 7521-7521 (1994)
Junshan Li et al.
ChemSusChem, 12(7), 1451-1458 (2019-01-25)
Co-Sn solid-solution nanoparticles with Sn crystal structure and tuned metal ratios were synthesized by a facile one pot solution-based procedure involving the initial reduction of a Sn precursor followed by incorporation of Co within the Sn lattice. These nanoparticles were
Thin Solid Films, 251, 19-19 (1994)

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