A8509
Lithium acetoacetate
≥90% (HPLC)
Synonym(s):
Acetoacetic acid lithium salt
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About This Item
Linear Formula:
CH3COCH2COOLi
CAS Number:
Molecular Weight:
108.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
5774841
Product Name
Lithium acetoacetate, ≥90% (HPLC)
InChI
1S/C4H6O3.Li/c1-3(5)2-4(6)7;/h2H2,1H3,(H,6,7);/q;+1/p-1
SMILES string
[Li+].CC(=O)CC([O-])=O
InChI key
UTLRZTUJSMCBHB-UHFFFAOYSA-M
assay
≥90% (HPLC)
form
powder
storage temp.
−20°C
Quality Level
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Application
Lithium acetoacetate can be used as an acetoacetate standard for the measurement of acetoacetate in biological samples. It can also be used for the preparation of sodium acetoacetate.
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Eun Ae Jeong et al.
Experimental neurology, 232(2), 195-202 (2011-09-24)
Similar to fasting, the ketogenic diet (KD) has anti-inflammatory effects and protects against excitotoxicity-mediated neuronal cell death. Recent studies have shown that peroxisome proliferator-activated receptor (PPAR)γ has anti-inflammatory effects in seizure animal models. However, the exact mechanisms underlying the anti-inflammatory
Seppo Parkkila et al.
Chemical communications (Cambridge, England), 48(29), 3551-3553 (2012-03-03)
Acetoacetic acid and R-3-hydroxy-butyric acid (BHB) are "ketone bodies", metabolites produced during the ketogenic diet. We discovered that they inhibit in the submicromolar-micromolar range several carbonic anhydrase (CA, EC 4.2.1.1) isoforms involved in relevant physiologic processes such as lipogenesis and
Hao Liang et al.
Journal of Cancer, 10(16), 3735-3745 (2019-07-25)
BDH2 is a short-chain dehydrogenase/reductase family member involved in several biological and pathological processes, including the utilization of cytosolic ketone bodies, immunocyte regulation and tumor progression. In this study, we first revealed that BDH2 was downregulated in HCC tissues by
Mathieu Coincon et al.
The Journal of biological chemistry, 287(43), 36208-36221 (2012-08-22)
Crystal structures of divalent metal-dependent pyruvate aldolase, HpaI, in complex with substrate and cleavage products were determined to 1.8-2.0 Å resolution. The enzyme·substrate complex with 4-hydroxy-2-ketoheptane-1,7-dioate indicates that water molecule W2 bound to the divalent metal ion initiates C3-C4 bond
Douglas Ganini et al.
Free radical biology & medicine, 51(3), 733-743 (2011-05-26)
Acetoacetate (AA) and 2-methylacetoacetate (MAA) are accumulated in metabolic disorders such as diabetes and isoleucinemia. Here we examine the mechanism of AA and MAA aerobic oxidation initiated by myoglobin (Mb)/H(2)O(2). We propose a chemiluminescent route involving a dioxetanone intermediate whose
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