M81705
Dimethyl sulfone
98%
Synonym(s):
Methyl sulfone
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About This Item
Linear Formula:
(CH3)2SO2
CAS Number:
Molecular Weight:
94.13
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
200-665-9
Beilstein/REAXYS Number:
1737717
MDL number:
Product Name
Dimethyl sulfone, 98%
InChI key
HHVIBTZHLRERCL-UHFFFAOYSA-N
InChI
1S/C2H6O2S/c1-5(2,3)4/h1-2H3
SMILES string
CS(C)(=O)=O
assay
98%
form
crystals
bp
238 °C (lit.)
mp
107-109 °C (lit.)
Quality Level
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Application
Dimethyl sulfone (DMSO2) can undergo:
DMSO2 can also be used as an electrolyte over a wide range of temperatures (110–150°C) for electrodeposition of aluminum.
- Acylation with N-acylbenzotriazoles to synthesize β-keto sulfones.
- α-Monoarylation via palladium-catalyzed Negishi coupling reaction to synthesize benzylic sulfones.
- One-step olefination of alcohols in the presence of ruthenium pincer complex as a catalyst.
DMSO2 can also be used as an electrolyte over a wide range of temperatures (110–150°C) for electrodeposition of aluminum.
Storage Class
11 - Combustible Solids
wgk
WGK 1
flash_point_f
289.4 °F - closed cup
flash_point_c
143.00 °C - closed cup
ppe
Eyeshields, Gloves, type N95 (US)
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Direct catalytic olefination of alcohols with sulfones.
Srimani D, et al.
Angewandte Chemie (International ed. in English), 53(41), 11092-11095 (2014)
Efficient conversion of sulfones intoβ-keto sulfones by N-acylbenzotriazoles.
Katritzky AR, et al.
The Journal of Organic Chemistry, 68(4), 1443-1446 (2003)
Studies on the AlCl3/dimethylsulfone (DMSO2) electrolytes for the aluminum deposition processes.
Jiang T, et al.
Surface and Coatings Technology, 201(14), 6309-6317 (2007)
Gaoqing Yuan et al.
Chemical communications (Cambridge, England), 48(60), 7513-7515 (2012-06-26)
With atmospheric oxygen as the oxidant, a novel copper(I)-catalyzed synthesis of aryl methyl sulfones from aryl halides and widely available DMSO is described. The procedure tolerates aryl halides with various functional groups (such as methoxy, acetyl, chloro, fluoro and nitro
Burkhard Kloesch et al.
Life sciences, 89(13-14), 473-478 (2011-08-09)
Reactive oxygen species (ROS) are highly diffusable and reactive molecules which modulate gene transcription, particularly of pro-inflammatory cytokines which play a crucial role in the nascency and progression of chronic inflammatory diseases such as rheumatoid arthritis (RA) and osteoarthritis (OA).
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