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Merck

02070595

Camphor (dl)

primary reference standard

Synonym(s):

(±)-Camphor, 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
76-22-2
Molecular Weight:
152.23
UNSPSC Code:
85151701
NACRES:
NA.24
PubChem Substance ID:
329747385
EC Number:
200-945-0
Beilstein/REAXYS Number:
1907611
MDL number:
MFCD00074738

Key Documents

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Product Name

Camphor (dl), primary reference standard

SMILES string

[H][C@](CC1=O)(CC2)C(C)(C)[C@]12C

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

grade

primary reference standard

vapor density

5.2 (vs air)

vapor pressure

4 mmHg ( 70 °C)

shelf life

limited shelf life, expiry date on the label

expl. lim.

3.5 %

manufacturer/tradename

HWI

bp

204 °C (lit.)

mp

175-177 °C (lit.)

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care

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Related Categories

Application

Reference Standard in the analysis of herbal medicinal products

General description

Produced and qualified by HWI pharma services GmbH.
Exact content by quantitative NMR can be found on the certificate.

Hazard Classifications

Acute Tox. 4 Inhalation - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

signalword

Danger

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 1

flash_point_f

147.9 °F - closed cup

flash_point_c

64.4 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
HWI00167-5
HWI00167-4
HWI00167-3
HWI00167-2
HWI00167

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I Jiménez-Díaz et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 936, 80-87 (2013-09-06)
UV-filters are widely used in many personal care products and cosmetics. Recent studies indicate that some organic UV-filters can accumulate in biota and act as endocrine disruptors, but there are few studies on the occurrence and fate of these compounds
Yali V Zhang et al.
Nature neuroscience, 16(10), 1468-1476 (2013-09-10)
Animals tend to reject bitter foods. However, long-term exposure to some unpalatable tastants increases acceptance of these foods. Here we show that dietary exposure to an unappealing but safe additive, camphor, caused the fruit fly Drosophila melanogaster to decrease camphor
Skrollan Stockinger et al.
Journal of chromatography. A, 1269, 346-351 (2012-08-23)
Novel 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes immobilized to poly(dimethylsiloxane) phases are presented. Immobilized 3-(perfluoroalkanoyl)-(1R)-camphorate nickel complexes with a trifluoromethyl (CF(3); nickel(II)-bis[(1R,4S)-3-trifluoromethanoyl-10-propylenoxycamphor]-polysiloxane Ni(tfpc)(2)@PS) and a heptafluoropropyl-substituent (C(3)F(7); nickel(II)-bis[(1R,4S)-3-heptafluorobutanoyl-10-propylenoxycamphor]-polysiloxane Ni(hfpc)(2)@PS) were synthesized, characterized and immobilized to polysiloxane. Ni(hfpc)(2)@PS was immobilized with a selector content
Hiroyuki Yamashita et al.
Pharmaceutical research, 30(1), 70-80 (2012-08-22)
Although a number of studies have reported that cocrystals can form by heating a physical mixture of two components, details surrounding heat-induced cocrystal formation remain unclear. Here, we attempted to clarify the thermal behavior of a physical mixture and cocrystal
Christian Merten et al.
The journal of physical chemistry. A, 116(27), 7329-7336 (2012-06-06)
In the present work, the first observation of strong resonance Raman optical activity (RROA) involving more that one resonant electronic state is reported. The chiral transition metal complex bis-(trifluoroacetylcamphorato) copper(II), abbreviated Cu(tfc)(2), exhibits both resonance Raman (RR) and RROA spectra
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