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Merck

36192

Phenmedipham

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C16H16N2O4
CAS Number:
13684-63-4
Molecular Weight:
300.31
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329755334
EC Number:
237-199-0
Beilstein/REAXYS Number:
2395027
MDL number:
MFCD00055419

Key Documents

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Product Name

Phenmedipham, PESTANAL®, analytical standard

InChI key

IDOWTHOLJBTAFI-UHFFFAOYSA-N

InChI

1S/C16H16N2O4/c1-11-5-3-6-12(9-11)18-16(20)22-14-8-4-7-13(10-14)17-15(19)21-2/h3-10H,1-2H3,(H,17,19)(H,18,20)

SMILES string

COC(=O)Nc1cccc(OC(=O)Nc2cccc(C)c2)c1

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

Quality Level

100

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Application

Phenmedipham may be used as a reference standard for the determination of the analyte in oranges by high-performance liquid chromatography-triple-quadrupole mass spectrometry in combination with QuEChERS method.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Phenmedipham is a carbanilate herbicide, used primarily to control broad-leaved weeds in sugar beet harvest and spinach.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Environment
GHS09

signalword

Warning

hcodes

H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

Storage Class

11 - Combustible Solids

wgk

WGK 2

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ0648
BCCC8369
BCBW2738
BCBV8180

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Voltammetric determination of phenmedipham herbicide using a multiwalled carbon nanotube paste electrode.
Demir E and Inam R
Turkish Journal of Chemistry, 42(4), 997-1007 (2018)
Sara C Novais et al.
Ecotoxicology (London, England), 21(1), 213-224 (2011-09-06)
The soil oligochaete Enchytraeus albidus is a standard test organism used in biological testing for Environmental Risk Assessment (ERA). Although effects are known at acute and chronic level through survival, reproduction and avoidance behaviour endpoints, very little is known at
Sara C Novais et al.
Chemosphere, 79(2), 233-237 (2010-02-06)
Enchytraeids are important inhabitants of a wide variety of soil types and suitable test organisms for environmental risk assessment through the determination of effects on survival and reproduction. In this study, the effect of pesticides with different modes of action
Thomas Müller et al.
Pest management science, 58(12), 1243-1249 (2002-12-13)
Ethoxylates of rapeseed oil and of methylated rapeseed oil were synthesized and tested as adjuvants for 2,4-D and phenmedipham. Provided they had less than 6 units of ethylene oxide (EO), 1.0 to 10 g litre(-1) ethoxylates in water induced droplet
Weed management in fresh market spinach (Spinacia oleracea) with phenmedipham and cycloate.
Lati RN, et al.
Weed Technology, 29(1), 101- 107 (2015)
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