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Merck

50843

D-Camphor

analytical standard

Synonym(s):

2-Bornanone, 2-Camphanone

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About This Item

Empirical Formula (Hill Notation):
C10H16O
CAS Number:
Molecular Weight:
152.23
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
85151701
EC Number:
207-355-2
MDL number:
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Product Name

D-Camphor, analytical standard

InChI key

DSSYKIVIOFKYAU-XCBNKYQSSA-N

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

SMILES string

CC1(C)[C@@H]2CC[C@@]1(C)C(=O)C2

grade

analytical standard

vapor density

5.24 (vs air)

vapor pressure

4 mmHg ( 70 °C)

assay

≥97.5% (GC)

optical activity

[α]/D +43.0±2.0°, c = 10 in ethanol

autoignition temp.

870 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

3.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

178-182 °C (lit.)

application(s)

cleaning products
cosmetics
flavors and fragrances
food and beverages
personal care

format

neat

Quality Level

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

D-Camphor is an acyclic terpenoid, that occurs naturally in the wood of Cinnamomum camphora.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

target_organs

Lungs

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 1

flash_point_f

147.2 °F - closed cup

flash_point_c

64 °C - closed cup


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The Pharmacology of Chinese Herbs, Second Edition (1998)
R E White et al.
Archives of biochemistry and biophysics, 228(2), 493-502 (1984-02-01)
Three alicyclic compounds (D-camphor, adamantanone, adamantane) were found to be hydroxylated by the cytochrome P-450 isoenzymes P-450cam and P-450LM2. With P-450cam as the catalyst only one product was formed from each of the substrates: 5-exohydroxycamphor, 5-hydroxyadamantanone, and 1-adamantanol. With P-450LM2
Gustav Georg Belz et al.
Phytomedicine : international journal of phytotherapy and phytopharmacology, 10 Suppl 4, 61-67 (2003-06-17)
Independent, double-blinded, randomized, placebo-controlled studies using sublingual/oral administration of D-camphor, an extract from fresh crataegus berries, and a combination of the two (CCC) yielded the following results: Both the D-camphor and the extract from fresh crataegus berries, the components of
Equilibrium states and dynamic reactions of iron in the camphor monoxygenase system.
I C Gunsalus et al.
Advances in experimental medicine and biology, 74, 254-262 (1976-01-01)
J Vilaplana et al.
Actas dermo-sifiliograficas, 98(5), 345-346 (2007-06-09)
We report a case of allergic contact dermatitis due to alcamphor present in a flushing solution used by a 58-year-old woman. It is the first case described in our Division of Allergy and the second one reported in the literature.

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