516813
Hydrogen peroxide solution
50 wt. % in H2O, stabilized
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About This Item
Empirical Formula (Hill Notation):
H2O2
CAS Number:
Molecular Weight:
34.01
UNSPSC Code:
12352304
NACRES:
NA.21
PubChem Substance ID:
EC Number:
231-765-0
Beilstein/REAXYS Number:
3587191
MDL number:
Assay:
48-52% H2O2 basis (by KMnO4, titration)
Concentration:
50 wt. % in H2O
agency
suitable for EPA 200.7
Quality Level
vapor pressure
23.3 mmHg ( 30 °C)
assay
48-52% H2O2 basis (by KMnO4, titration)
reaction suitability
reaction type: C-H Activation, reagent type: catalyst, reagent type: oxidant
greener alternative product characteristics
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
concentration
50 wt. % in H2O
mp
−40 °C
solubility
water: soluble at 20 °C
density
1.197 g/mL at 20 °C
greener alternative category
storage temp.
2-8°C
SMILES string
OO
InChI
1S/H2O2/c1-2/h1-2H
InChI key
MHAJPDPJQMAIIY-UHFFFAOYSA-N
General description
The product is a 50% solution of hydrogen peroxide in water. Hydrogen peroxide is more commonly being used as a green oxidizing agent. It is a better alternative to other oxidants because it has high active oxygen content and the by-product is water.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of the 12 Principles of Green Chemistry. This product has been enhanced for catalysis. Click here for more information.
Application
Hydrogen peroxide solution may be used as an oxidizing agent in the following reactions:
- Epoxidation of alkenes in the presence of homogeneous metal catalyst.
- Oxidative halogenation in the presence of metal catalyst.
- Oxidation of sulfides to sulfoxides and sulfones in the presence of polymer immobilised catalyst.
Other Notes
Contains proprietary inorganic tin-based stabilizer
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Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Ox. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
Storage Class
5.1B - Oxidizing hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
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Oxidative halogenation with ?green? oxidants: oxygen and hydrogen peroxide.
Podgorsek A, et al.
Angewandte Chemie (International Edition in English), 48(45), 8424-8450 (2009)
Efficient and selective hydrogen peroxide-mediated oxidation of sulfides in batch and segmented and continuous flow using a peroxometalate-based polymer immobilised ionic liquid phase catalyst.
Doherty S, et al.
Green Chemistry, 17(3), 1559-1571 (2015)
Recent developments on the epoxidation of alkenes using hydrogen peroxide as an oxidant.
Grigoropoulou G, et al.
Green Chemistry, 5(1), 1-7 (2003)