265640
Tin
powder, <150 μm, 99.5% trace metals basis
Sinónimos:
Sn
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Fórmula empírica (notación de Hill):
Sn
Número CAS:
Peso molecular:
118.71
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
11101716
EC Number:
231-141-8
MDL number:
Servicio técnico
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Permítanos ayudarleQuality Level
assay
99.5% trace metals basis
form
powder
reaction suitability
core: tin, reagent type: catalyst
resistivity
11 μΩ-cm, 20°C
particle size
<150 μm
bp
2270 °C (lit.)
mp
231.9 °C (lit.)
density
7.310 g/mL at 25 °C (lit.)
SMILES string
[Sn]
InChI
1S/Sn
InChI key
ATJFFYVFTNAWJD-UHFFFAOYSA-N
General description
Tin is an efficient catalyst for the polycondensation of lactic acid to synthesize poly(lactic acid).
Application
With HCl, reduces a variety of functional groups; stereoselective allylation of carbonyl compounds; in situ generation of tin enolates for directed aldol reactions.
Clase de almacenamiento
13 - Non Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Improving lactic acid melt polycondensation: The role of co-catalyst
Marques DS, et al.
Journal of Applied Polymer Science, 128, 2145-2151 (2013)
D B Shpakovsky et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14568-14582 (2012-10-12)
Four new organotin(IV) complexes of bis-(2,6-di-tert-butylphenol)tin(IV) dichloride [(tert-Bu-)(2)(HO-Ph)](2)SnCl(2) (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl-pyrimidine (MPMTH), 2-mercapto-pyridine (PYTH) and 2-mercapto-benzothiazole (MBZTH), of formulae {[(tert-Bu-)(2)(HO-Ph)](2)Sn(PMT)(2)} (2), {[(tert-Bu-)(2)(HO-Ph)](2)Sn(MPMT)(2)} (3), {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(PYT)} (4) and {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(MBZT)} (5), have been synthesized and characterized by elemental
Lun Li et al.
Journal of the American Chemical Society, 135(4), 1213-1216 (2013-01-15)
Single-layer single-crystalline SnSe nanosheet with four-atomic thickness of ~1.0 nm and lateral size of ~300 nm is presented here by using a one-pot synthetic method. It is found that 1,10-phenanthroline plays an important role in determining the morphology of the