G3407
Glutaric acid
99%
Sinónimos:
1,3-Propanedicarboxylic acid, 1,5-Pentanedioic acid
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Fórmula lineal:
HOOC(CH2)3COOH
Número CAS:
Peso molecular:
132.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
203-817-2
Beilstein/REAXYS Number:
1209725
MDL number:
Assay:
99%
Servicio técnico
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Permítanos ayudarleQuality Level
assay
99%
bp
200 °C/20 mmHg (lit.)
mp
95-98 °C (lit.)
solubility
water: soluble 5 mg/mL, clear to slightly hazy, colorless to faintly yellow, alcohol: soluble(lit.), chloroform: soluble(lit.)
SMILES string
OC(=O)CCCC(O)=O
InChI
1S/C5H8O4/c6-4(7)2-1-3-5(8)9/h1-3H2,(H,6,7)(H,8,9)
InChI key
JFCQEDHGNNZCLN-UHFFFAOYSA-N
General description
Glutaric acid is a pentanedioic acid. On exposure to X-rays, glutaric acid crystals generate two stable free radicals. These free radicals have been investigated by electron nuclear double resonance (ENDOR) technique. Presence of glutaric acid in urine and plasma is an indicator of type I glutaric aciduria (GA-I).
Glutaric acid is an aliphatic acid used as building block for the synthesis of polyesters, and polyamides.
Glutaric acid (Pentanedioic Acid) is a linear dicarboxylic acid. It has been prepared by oxidizing cyclopentane, cyclopentanol and cyclopentanone.
Glutaric acid (Pentanedioic Acid) is a linear dicarboxylic acid. It has been prepared by oxidizing cyclopentane, cyclopentanol and cyclopentanone.
Glutaric acid is formed as an intermediate during the catabolism of lysine in mammals. Electron spin resonance spectra of radical (CO2H)CH2CH2CH(CO2H formed in glutaric acid crystal after γ-irradiation is reported to remains trapped in it. Polymorphism of Glycine-glutaric acid co-crystals has been studied by single crystal X-ray diffraction and Raman spectroscopy.
Application
Glutaric acid may be employed as starting reagent in the synthesis of glutaric anhydride.
Glutaric acid may be used for the following studies:
- Complexation with DL-lysine. Complexes have been reported to possess zwitterionic lysinium ions (positively charged) and semi-glutarate ions (negatively charged).
- Synthesis of complexes with L-arginine and L-histidine.
- Preparation of glycine-glutaric acid co-crystals. Phase transition studies of these cocrystals have been reported by single-crystal X-ray diffraction, polarized Raman spectroscopy and differential scanning calorimetry.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A
Clase de almacenamiento
8A - Combustible corrosive hazardous materials
wgk
WGK 1
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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Electron spin resonance of (CO2H) CH2CH2CH (CO2H) in irradiated glutaric acid.
Horsfield A, et al.
Molecular Physics, 4(2), 169-175 (1961)
Exploring rearrangements along the fragmentation of glutaric acid negative ion: a combined experimental and theoretical study
Basem K et al.
Rapid Communications in Mass Spectrometry, 24, 1198-1206 (2010)
D H Morton et al.
American journal of medical genetics, 41(1), 89-95 (1991-10-01)
We have diagnosed type I glutaric aciduria (GA-I) in 14 children from 7 Old Order Amish families in Lancaster County, Pennsylvania. An otherwise rare disorder, GA-I appears to be a common cause of acute encephalopathy and cerebral palsy among the