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Merck

31598

4-Aminobiphenyl

analytical standard

Sinónimos:

4-Aminodiphenyl, 4-Biphenylamine, 4-Biphenylylamine, 4-Phenylaniline, Biphenyl-4-ylamine, NSC 7660, Xenylamine

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Fórmula lineal:
C6H5C6H4NH2
Número CAS:
92-67-1
Peso molecular:
169.22
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
329753843
EC Number:
202-177-1
Beilstein/REAXYS Number:
386533
MDL number:
MFCD00007879

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InChI key

DMVOXQPQNTYEKQ-UHFFFAOYSA-N

InChI

1S/C12H11N/c13-12-8-6-11(7-9-12)10-4-2-1-3-5-10/h1-9H,13H2

SMILES string

Nc1ccc(cc1)-c2ccccc2

grade

analytical standard

autoignition temp.

842 °F

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

bp

191 °C/15 mmHg (lit.)

mp

52-54 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

Quality Level

100

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General description

4-Aminobiphenyl is classified under the aromatic amine group of compounds.
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

4-Aminobiphenyl has been used as an analytical reference standard for the analysis of 4-aminobiphenyl in food packaging materials by liquid chromatography-full scan-high resolution mass spectrometry (LC-HRMS).
It may be used as an analytical reference standard for the determination of 4-aminobiphenyl in:
  • Particulate phase mainstream cigarette smoke samples by solid-phase extraction (SPE) and gas chromatography coupled to MS equipped with selected ion monitoring (SIM) mode of detection as well as simultaneous distillation and extraction (SDE) and GC-MS with SIM detection.
  • Environmental water samples by hollow fiber-liquid phase microextraction (HF-LPME) and microemulsion electrokinetic chromatography (MEEKC).
  • Indoor and outdoor air samples by GC-MS.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

Health hazardExclamation mark
GHS08,GHS07

signalword

Danger

hcodes

H302,H350

Hazard Classifications

Acute Tox. 4 Oral - Carc. 1A

Clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
BCCJ4933
BCBW9520
BCBS7213V

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Analysis of polycyclic aromatic hydrocarbons, phenols and aromatic amines in particulate phase cigarette smoke using simultaneous distillation and extraction as a sole sample clean-up step.
Forehand JB, et al.
Journal of Chromatography A, 898(1), 111-124 (2000)
Determination of aromatic amines in environmental water sample by hollow fiber-liquid phase microextraction and microemulsion electrokinetic chromatography.
Lin Z, et al.
Journal of Chromatography A, 1217(26), 4507-4510 (2010)
Moinuddin et al.
Environmental toxicology, 29(5), 568-576 (2012-05-23)
4-Aminobiphenyl (4-ABP), an aromatic amine is a major environmental carcinogen found mainly in cigarette smoke. It has been vastly implicated in mutagenesis and cancer development. In this study, commercially available human placental DNA was exposed to 4-ABP (1.3 mM) in
Simultaneous determination of aliphatic and aromatic amines in indoor and outdoor air samples by gas chromatography-mass spectrometry.
Akyuz M.
Talanta, 71(1), 486-492 (2007)
Liquid chromatography-full scan-high resolution mass spectrometry-based method towards the comprehensive analysis of migration of primary aromatic amines from food packaging.
Mattarozzi M, et al.
Journal of Chromatography A, 1320(1), 96-102 (2013)
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