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Merck

31712

Fluazifop-P-butyl

PESTANAL®, analytical standard

Sinónimos:

Butyl (R)-2-[4-(5-trifluoromethyl-2-pyridyloxy)phenoxy]propionate

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Fórmula empírica (notación de Hill):
C19H20F3NO4
Número CAS:
79241-46-6
Peso molecular:
383.36
NACRES:
NA.24
PubChem Substance ID:
329753893
UNSPSC Code:
41116107
MDL number:
MFCD06199153

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InChI

1S/C19H20F3NO4/c1-3-4-11-25-18(24)13(2)26-15-6-8-16(9-7-15)27-17-10-5-14(12-23-17)19(20,21)22/h5-10,12-13H,3-4,11H2,1-2H3/t13-/m1/s1

SMILES string

CCCCOC(=O)[C@@H](C)Oc1ccc(Oc2ccc(cn2)C(F)(F)F)cc1

InChI key

VAIZTNZGPYBOGF-CYBMUJFWSA-N

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

Quality Level

100

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General description

Fluazifop-P-butyl belongs to the arylophenoxypropionate group of graminicides. It is a post-emergence herbicide that acts by inhibiting acetyl-CoA carboxylase enzyme activity, involved in the catalysis of the formation of malonyl-CoA during metabolism of lipids.

Application

Fluazifop-P-butyl may be used as a reference standard for the determination of the analyte:
  • In different varieties of lettuce (Lactuca sativum) by capillary gas chromatography with nitrogen–phosphorus detection (NPD).
  • In tea samples by modified QuEChERS (quick, easy, cheap, effective, rugged, and safe) sample preparation procedure combined with ultra-performance liquid chromatography-electrospray tandem mass spectrometry (UPLC/MS/MS).

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Flam. Liq. 3 - Repr. 2

Clase de almacenamiento

3 - Flammable liquids

wgk

WGK 3

flash_point_f

122.0 °F - closed cup - (External MSDS)

flash_point_c

50 °C - closed cup - (External MSDS)

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCL5292
BCCJ5805
BCBX4137

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Visite la Librería de documentos

Effect of fluazifop-p-butyl treatment on pigments and polyamines level within tissues of non-target maize plants.
Horbowicz M, et al.
Pesticide Biochemistry and Physiology, 107(1), 78- 85 (2013)
A multi-residue method for fast determination of pesticides in tea by ultra performance liquid chromatography- electrospray tandem mass spectrometry combined with modified QuEChERS sample preparation procedure.
Chen G, et al.
Food Chemistry, 125(4), 1406- 1411 (2011)
Fluazifop-P-butyl (herbicide) affects richness and structure of soil bacterial communities.
Darine T, et al.
Soil Biology and Biochemistry, 81, 89- 97 (2015)
Simplified multiresidue method for determination of pesticide residues in lettuce by gas chromatography with nitrogen- phosphorus detection.
Fenoll J, et al.
Analytical and Bioanalytical Chemistry, 389(2), 643- 651 (2007)
N W McCracken et al.
Biochemical pharmacology, 45(1), 31-36 (1993-01-07)
In the present study, the distribution and nature of esterases in the rat which hydrolysed fluazifop-butyl, carbaryl, paraoxon and phenylacetate were investigated. Vmax and Km values for the hydrolysis reactions were determined. Fluazifop-butyl was hydrolysed to fluazifop by rat liver
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