70956
1-Butyl-3-methylimidazolium hexafluorophosphate
≥97.0% (HPLC)
Sinónimos:
BMIMPF6
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Fórmula empírica (notación de Hill):
C8H15F6N2P
Número CAS:
Peso molecular:
284.18
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
≥97.0% (HPLC)
Form:
liquid
Servicio técnico
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Permítanos ayudarleQuality Level
assay
≥97.0% (HPLC)
form
liquid
greener alternative product characteristics
Catalysis
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refractive index
n20/D 1.411 (lit.)
density
1.38 g/mL at 20 °C (lit.)
greener alternative category
SMILES string
F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
InChI
1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
InChI key
IXQYBUDWDLYNMA-UHFFFAOYSA-N
General description
BMIMPF6 is used as an efficient reaction medium for various synthetic and catalytic transformations.
1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.
1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF6.
Application
1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.
It can also be used as a medium for reactions such as:
It can also be used as a medium for reactions such as:
- Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.
- Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.
- Lipase-catalyzed enantioselective acylation of allylic alcohols.
- Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.
Features and Benefits
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign and has been enhanced for catalytic efficiency. Click here for more information.
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Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
Clase de almacenamiento
10 - Combustible liquids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
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J. Howarth et al.
Tetrahedron Letters, 41, 10319-10319 (2000)
T. Itoh et al.
Chemistry Letters (Jpn), 262-262 (2001)
Lipase-catalyzed enantioselective acylation in the ionic liquid solvent system: reaction of enzyme anchored to the solvent.
Itoh T, et al.
Chemistry Letters (Jpn), 30(3), 262-263 (2001)