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Merck

269336

Peracetic acid solution

32 wt. % in dilute acetic acid

Sinónimos:

Peroxyacetic acid

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Fórmula lineal:
CH3CO3H
Número CAS:
Peso molecular:
76.05
PubChem Substance ID:
UNSPSC Code:
12352106
Beilstein/REAXYS Number:
1098464
MDL number:
Concentration:
29.0-35% (by sodium thiosulfate, titration), 32 wt. % in dilute acetic acid
Form:
liquid
Servicio técnico
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vapor pressure

20 mmHg ( 25 °C)

Quality Level

form

liquid

composition

acetic acid, 40-45%

reaction suitability

reagent type: oxidant

concentration

29.0-35% (by sodium thiosulfate, titration), 32 wt. % in dilute acetic acid

impurities

<6.0% hydrogen peroxide

refractive index

n20/D 1.3876

pH

<1

density

1.13 g/mL at 25 °C

shipped in

wet ice

storage temp.

2-8°C

SMILES string

CC(=O)OO

InChI

1S/C2H4O3/c1-2(3)5-4/h4H,1H3

InChI key

KFSLWBXXFJQRDL-UHFFFAOYSA-N

General description

Peracetic acid (PAA) is a peroxy acid that is commonly used as an excellent oxidizing agent in organic synthesis. It is also used as a bleaching and sterilizing agent.

Application

Peracetic acid solution (32 wt. % in dilute acetic acid) can be used as an oxidant for the selective epoxidation of aliphatic terminal alkenes in the presence of manganese(II) perchlorate as the catalyst at ambient temperature. It is also used to oxidize sulfides, selenides, and amines.

Features and Benefits

  • Easily synthesized
  • Environmentally benign reagent



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Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Met. Corr. 1 - Org. Perox. D - Skin Corr. 1 - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 2

flash_point_f

132.8 °F

flash_point_c

56 °C



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Ultrasound-assisted MnO2 catalyzed homolysis of peracetic acid for phenol degradation: The assessment of process chemistry and kinetics.
Rokhina EV, et al.
Chemical Engineering Journal, 276, 91-96 (2015)
Eagleson M.
Concise Encyclopedia Chemistry, 894-894 (1994)
Mi Li et al.
Biotechnology for biofuels, 10, 237-237 (2017-12-08)
Hydrothermal pretreatment using liquid hot water (LHW) is capable of substantially reducing the cell wall recalcitrance of lignocellulosic biomass. It enhances the saccharification of polysaccharides, particularly cellulose, into glucose with relatively low capital required. Due to the close association with