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Merck

8.18642

tert-Butyldimethylchlorosilane

for synthesis

Synonym(s):

tert-Butyldimethylchlorosilane, tert-Butyldimethylsilyl chloride, tert-Butylchlorodimethylsilane, TBDMSCl

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About This Item

Linear Formula:
(CH3)3CSi(CH3)2Cl
CAS Number:
Molecular Weight:
150.72
UNSPSC Code:
12352103
EC Index Number:
242-042-4
NACRES:
NA.22
MDL number:
Assay:
≥97.0% (GC)
Form:
crystals
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Quality Level

assay

≥97.0% (GC)

form

crystals

mp

87-90 °C

transition temp

flash point 22 °C

storage temp.

2-30°C

SMILES string

[Si](Cl)(C(C)(C)C)(C)C

InChI

1S/C6H15ClSi/c1-6(2,3)8(4,5)7/h1-5H3

InChI key

BCNZYOJHNLTNEZ-UHFFFAOYSA-N

Application


  • Anionic polymerization initiator synthesis: Research on mono-lithium based initiators for polybutadiene synthesis highlights the steric effects of TBDMSCl as a component (Zhu et al., 2017).

  • Environmental analysis: TBDMSCl is used in the analysis of bisphenol compounds in wastewater, indicating its role in complex sample preparation processes (Cesen et al., 2018).

  • Derivatization in chemical analysis: The reagent is utilized for in situ derivatization extraction techniques for detecting nerve agent degradation products (Chinthakindi et al., 2014).

Analysis Note

Assay (GC, area%): ≥ 97.0 % (a/a)
Melting range (lower value): ≥ 87 °C
Melting range (upper value): ≤ 91 °C
Identity (IR): passes test


signalword

Danger

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - Flam. Sol. 1 - Skin Corr. 1A

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 2

flash_point_f

71.6 °F - closed cup

flash_point_c

22 °C - closed cup



Certificates of Analysis (COA)

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