416665
tert-Butyl hydroperoxide solution
5.0-6.0 M in decane
Synonym(s):
1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP
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About This Item
form
liquid
Quality Level
reaction suitability
reagent type: oxidant
concentration
5.0-6.0 M in decane, 55.4-65.1% (Thiosulphate, titration)
impurities
<4% water
refractive index
n20/D 1.402
density
0.808 g/mL at 25 °C
storage temp.
2-8°C
SMILES string
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
General description
Application
osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions
catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary
oxidation of dibenzothiophenes
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Danger
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. D - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
Storage Class
5.2 - Organic peroxides and self-reacting hazardous materials
flash_point_f
109.4 °F - closed cup
flash_point_c
43 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Regulatory Listings
Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.
Class II Designated Chemical Substances
prtr
Group 5: Self-reactive substances + Organic peroxides + Hazardous rank II + 2nd self-reactive materials
fsl
Substances Subject to be Indicated Names
ishl_indicated
Substances Subject to be Notified Names
ishl_notified
416665-25ML:4.548173385471E12 + 416665-100ML:4.548173385464E12
jan
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