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450995

Manganese(II) chloride

AnhydroBeads™, −10 mesh, 99.999% trace metals basis

Synonym(s):

Manganese dichloride, Sacchite

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About This Item

Linear Formula:
MnCl2
CAS Number:
7773-01-5
Molecular Weight:
125.84
NACRES:
NA.23
PubChem Substance ID:
24868596
UNSPSC Code:
12352302
MDL number:
MFCD00011114
eCl@ss:
38190105
Assay:
99.999% trace metals basis
Grade:
synthesis grade
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grade

synthesis grade

product line

AnhydroBeads™

assay

99.999% trace metals basis

reaction suitability

core: manganese

impurities

≤15.0 ppm Trace Metal Analysis

particle size

−10 mesh

mp

652 °C (lit.)

density

2.98 g/mL at 25 °C (lit.)

application(s)

battery precursors
catalysts
electroplating
material synthesis precursor

SMILES string

Cl[Mn]Cl

InChI

1S/2ClH.Mn/h2*1H;/q;;+2/p-2

InChI key

GLFNIEUTAYBVOC-UHFFFAOYSA-L

Application

A novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state. Also used in the formation of an active Mn(0) species useful for radical cyclization reactions.

Legal Information

AnhydroBeads is a trademark of Sigma-Aldrich Co. LLC

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Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - STOT RE 2

target_organs

Brain

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Regulatory Listings

Regulatory Listings are mainly provided for chemical products. Only limited information can be provided here for non-chemical products. No entry means none of the components are listed. It is the user’s obligation to ensure the safe and legal use of the product.

Class I Designated Chemical Substances

prtr

Substances Subject to be Indicated Names

ishl_indicated

Substances Subject to be Notified Names

ishl_notified

450995-5G:4.54817401002E12 + 450995-25G:4.548174010013E12

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Certificates of Analysis (COA)

Lot/Batch Number
0000534693
0000522304
0000522304
0000534693
0000036203

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Articles

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Abbati, G.L. et al.
Inorganic Chemistry, 37, 1430-1430 (1998)
Tang, J. et al.
Tetrahedron, 55, 1893-1893 (1999)
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